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Synthesis and investigation of iron (II) dioximates with arsine derivatives by Moessbauer and IR spectroscopy

Journal Article · · Sov. J. Coordinat. Chem.; (United States)
OSTI ID:7191392
New compounds with the formula (Fe/sup II/(dioximate)/sub 2/L/sub 2/), where dioximate stands for monodeprotonated anions of dimethylglyoxime (dmgH), diphenylglyoxime (dfgH), 1,2-cyclohexanedione dioxime (nioxH), and ..cap alpha..-furildioxime (furgH), and L stands for di-n-butylphenylarsine (AsBut/sub 2/Ph) and triethylarsine (AsEt/sub 3/), have been investigated by Moessbauer and IR spectroscopy. The Moessbauer spectra of the compounds indicated at 80 and 300/sup 0/K consist of doublets, whose parameters correspond to the low-spin state of iron (II).
OSTI ID:
7191392
Journal Information:
Sov. J. Coordinat. Chem.; (United States), Journal Name: Sov. J. Coordinat. Chem.; (United States) Vol. 13:8; ISSN SJCCD
Country of Publication:
United States
Language:
English

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