Monocapped tris(dioxime) complexes of technetium(III): Synthesis and structural characterization of TcX(dioxime) sub 3 B-R (X = Cl, Br; dioxime = dimethylglyoxime, cyclohexanedione dioxime; R = CH sub 3 , C sub 4 H sub 9 )

Journal Article · Wed Sep 06 00:00:00 EDT 1989 · Inorganic Chemistry; (USA)

DOI:https://doi.org/10.1021/ic00317a004· OSTI ID:6985676

Treher, E N; Francesconi, L C; Gougoutas, J Z; Malley, M F; Nunn, A D ^[1]

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1. Squibb Institute for Medical Research, New Brunswick, NJ (USA)

Monocapped boronic acid adducts of technetium tris(dioxime) complexes (BATO), TcX(dioximeH){sub 2}(dioxime)B-R, where X = Cl or Br, dioxime = cyclohexanedione dioxime or dimethylglyoxime, and R = methyl or butyl, have been prepared by template synthesis starting with pertechnetate and stannous ion, (N(C{sub 4}H{sub 9}){sub 4})(TcOCl{sub 4}), or M{sub 2}(TcX{sub 6}) (M = NH{sub 4}, K; X = Cl, Br). These seven-coordinate Tc(III) compounds are the first examples of tris(dioxime) complexes in which one and only one oxygen of each of the three dioximes is joined to a common cap atom (boron). The crystal structures of three of the BATO complexes have been determined and are reported. The three dioxime oxygens on the uncapped end of the molecule are intramolecularly hydrogen bonded to two bridging protons. A halogen occupies the seventh coordination site. 34 refs., 4 figs., 8 tabs.

• OSTI ID: 6985676
• Journal Information: Inorganic Chemistry; (USA), Journal Name: Inorganic Chemistry; (USA) Vol. 28:18; ISSN 0020-1669; ISSN INOCA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
AMINES
CHEMICAL PREPARATION
CRYSTAL STRUCTURE
DATA
EXPERIMENTAL DATA
HALOGEN COMPOUNDS
HYDROXY COMPOUNDS
INFORMATION
NUMERICAL DATA
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
OXIMES
REFRACTORY METAL COMPOUNDS
SYNTHESIS
TECHNETIUM COMPOUNDS
TRANSITION ELEMENT COMPOUNDS