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Fate of avermectin B1a on citrus fruits. 1. Distribution and magnitude of the avermectin B sub 1a and sup 14 C residue on citrus fruits from a field study

Journal Article · · Journal of Agricultural and Food Chemistry; (USA)
OSTI ID:7190341
; ; ; ;  [1]
  1. Merck, Sharp and Dohme Research Labs., Three Bridges, NJ (USA)

An 8{mu}g/mL solution of ({sup 14}C)avermectin B{sub 1a}, the approximate field application rate, was applied to oranges, lemons, and grapefruit; a 10-fold higher rate was also applied to oranges. Immediately postapplication, {sup 14}C residues were 20-38 ng/g for the fruit treated at the field rate. Most of the residue was recovered in the surface solvent rinse at less than 2 weeks postapplication; however, after this time more of the residue was recovered from the rind fraction. The total recoveries of applied radioactivity were 61-90% and 33-50% at 1 and 12 weeks postapplication, respectively. The level of unextractable rind {sup 14}C residue from oranges treated at the 10{times} rate and harvested at 12 weeks (a worse case) was 4.9% of the applied dose (<2 ppb at the field rate). The inner pulp samples for all treatments had {sup 14}C residue levels below the detection limit of 0.4-0.8 ppb. The initial depletion half-life of avermectin B{sub 1a} was <1 week, with losses occurring within 30-40 min. For the 1-12-week postapplication period, the avermectin B{sub 1a} and {sup 14}C residue depletion half-lives were 20-38 and 56-98 days, respectively. Differences in the rate of dissipation of avermectin B{sub 1a} due to fruit type and application rate were observed.

OSTI ID:
7190341
Journal Information:
Journal of Agricultural and Food Chemistry; (USA), Journal Name: Journal of Agricultural and Food Chemistry; (USA) Vol. 37:1; ISSN 0021-8561; ISSN JAFCA
Country of Publication:
United States
Language:
English

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