Rotational analysis of the high-resolution infrared spectra of the [nu][sub 4] and [nu][sub 5] bands of formyl chloride
Journal Article
·
· Journal of Molecular Spectroscopy; (United States)
- Univ. of Kentucky, Lexington, KY (United States). Dept. of Chemistry
- Univ. of British Columbia, Vancouver, British Columbia (Canada). Dept. of Chemistry
- Univ. of Wisconsin, Kenosha, WI (United States). Dept. of Chemistry
The high-resolution infrared spectra of the low-lying [nu][sub 4] and [nu][sub 5] fundamentals of the transient molecule formyl chloride, HCOCl, are reported. Both type A/B hybrid bands have been analyzed in detail, providing rotational assignments for the HCO[sup 35]Cl and HCO[sup 37]Cl isotopomers. The excited state rotational and centrifugal distortion constants have been determined by fitting assignments over a wide range of J and K[sub a] values. No perturbations were detected in either band.
- DOE Contract Number:
- FG05-86ER13544
- OSTI ID:
- 7178928
- Journal Information:
- Journal of Molecular Spectroscopy; (United States), Journal Name: Journal of Molecular Spectroscopy; (United States) Vol. 168:1; ISSN JMOSA3; ISSN 0022-2852
- Country of Publication:
- United States
- Language:
- English
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Journal Article
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Wed Sep 01 00:00:00 EDT 1993
· Journal of Molecular Spectroscopy; (United States)
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OSTI ID:5623829
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Fri Jul 01 00:00:00 EDT 1994
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· Journal of Molecular Spectroscopy; (United States)
·
OSTI ID:6531497
Related Subjects
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400102* -- Chemical & Spectral Procedures
ACYL RADICALS
ACYLATION
ATMOSPHERIC CHEMISTRY
CARBON COMPOUNDS
CARBON MONOXIDE
CARBON OXIDES
CHALCOGENIDES
CHEMICAL REACTIONS
CHEMISTRY
CHLORINATED ALIPHATIC HYDROCARBONS
CHLORINE COMPOUNDS
DECOMPOSITION
FORMYL RADICALS
HALOGEN COMPOUNDS
HALOGENATED ALIPHATIC HYDROCARBONS
HYDROCHLORIC ACID
HYDROGEN COMPOUNDS
INFRARED SPECTRA
INORGANIC ACIDS
ORGANIC CHLORINE COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
OXIDATION
OXIDES
OXYGEN COMPOUNDS
PHOTOCHEMICAL REACTIONS
PHOTOLYSIS
RADICALS
REACTION INTERMEDIATES
SPECTRA
400102* -- Chemical & Spectral Procedures
ACYL RADICALS
ACYLATION
ATMOSPHERIC CHEMISTRY
CARBON COMPOUNDS
CARBON MONOXIDE
CARBON OXIDES
CHALCOGENIDES
CHEMICAL REACTIONS
CHEMISTRY
CHLORINATED ALIPHATIC HYDROCARBONS
CHLORINE COMPOUNDS
DECOMPOSITION
FORMYL RADICALS
HALOGEN COMPOUNDS
HALOGENATED ALIPHATIC HYDROCARBONS
HYDROCHLORIC ACID
HYDROGEN COMPOUNDS
INFRARED SPECTRA
INORGANIC ACIDS
ORGANIC CHLORINE COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
OXIDATION
OXIDES
OXYGEN COMPOUNDS
PHOTOCHEMICAL REACTIONS
PHOTOLYSIS
RADICALS
REACTION INTERMEDIATES
SPECTRA