The 2[nu][sub 1] band of HOCl

Journal Article · Tue Jun 01 04:00:00 EDT 1993 · Journal of Molecular Spectroscopy; (United States)

DOI:https://doi.org/10.1006/jmsp.1993.1137· OSTI ID:6531497

Cavazza, F; Di Lonardo, G; Fusina, L ^[1]; Escribano, R; Ortigoso, J ^[2]; Gomez, P C ^[3]

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1. Viale Risorgimento, Bologna (Italy)
2. Instituto de Estructura de la Materia, C.S.I.C., Madrid (Spain)
3. Univ. Complutense, Madrid (Spain)

The first overtone band of the O-H stretching mode in HOCL has been recorded between 6,700 and 7,250 cm[sup [minus]1] at a resolution of 0.017 cm[sup [minus]1], which is close to the Doppler limit. Two thousand fifty-four transitions for HO[sup 35]Cl and 876 for HO[sup 37]Cl were assigned and analyzed on the basis of a Watson-type Hamiltonian in the S reduction and I[sup r] representation. A set of precise spectroscopic parameters for the [nu][sub 1] = 2 state of both isotopomers has been determined. Band origins were located at 7,049.8132 and 7,049.8234 cm[sup [minus]1] for HO[sub 35]Cl and HO[sub 37]Cl, respectively.

• OSTI ID: 6531497
• Journal Information: Journal of Molecular Spectroscopy; (United States), Journal Name: Journal of Molecular Spectroscopy; (United States) Vol. 159:2; ISSN JMOSA3; ISSN 0022-2852
• Country of Publication: United States
• Language: English

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54 ENVIRONMENTAL SCIENCES
540110*
ATMOSPHERIC CHEMISTRY
CHEMICAL COMPOSITION
CHEMISTRY
CHLORINE COMPOUNDS
EARTH ATMOSPHERE
ELEMENTS
ENERGY LEVELS
FOURIER TRANSFORM SPECTROMETERS
HALOGEN COMPOUNDS
HALOGENS
HYDROGEN COMPOUNDS
INFRARED SPECTRA
MEASURING INSTRUMENTS
MOLECULES
NONMETALS
OXYGEN COMPOUNDS
SPECTRA
SPECTROMETERS
STRATOSPHERE