Iron-intercalated molybdenum disulfide obtained from single-layer dispersion

Journal Article · Mon Aug 01 04:00:00 EDT 1994 · Materials Research Bulletin; (United States)

DOI:https://doi.org/10.1016/0025-5408(94)90003-5· OSTI ID:7151337

Danot, M; Mansot, J L; Rouxel, J ^[1]; Golub, A S; Protzenko, G A; Novikov, Yu N ^[2]; Fabritchnyi, P B ^[3]

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1. CNRS-Univ. de Nantes (France). Lab. de Chimie des Solides
2. Russian Academy of Sciences, Moscow (Russian Federation). A.N. Nesmeyanov Inst. of Organoelement Compounds
3. Lomonosov Univ., Moscow (Russian Federation)

MoS[sub 2] intercalation compounds with transition metals could be of great interest for catalysis of petrochemical processes, and also from the magnetic point of view since, for two-dimensional metallic layers included into a diamagnetic matrix, unusual magnetic properties can be expected. Iron-intercalated molybdenum disulfide, obtained by flocculation of a MoS[sub 2] single-layer dispersion in the presence of ferrous sulfate, was studied by electron microscopy and Moessbauer spectroscopy. Iron was found to occur at both II and III oxidation states between the MoS[sub 2] layers. The formation mechanism of this intercalated compound and its composition are discussed.

• OSTI ID: 7151337
• Journal Information: Materials Research Bulletin; (United States), Journal Name: Materials Research Bulletin; (United States) Vol. 29:8; ISSN MRBUAC; ISSN 0025-5408
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
CATALYSTS
CHALCOGENIDES
CHEMICAL PREPARATION
CHEMICAL PROPERTIES
CHEMICAL REACTION KINETICS
CLATHRATES
IRON COMPOUNDS
IRON SULFATES
KINETICS
MOLYBDENUM COMPOUNDS
MOLYBDENUM SULFIDES
OXYGEN COMPOUNDS
REACTION KINETICS
REFRACTORY METAL COMPOUNDS
SULFATES
SULFIDES
SULFUR COMPOUNDS
SYNTHESIS
TRANSITION ELEMENT COMPOUNDS
USES
VALENCE