Intercalation Pseudocapacitance of Exfoliated Molybdenum Disulfide for Ultrafast Energy Storage

Yoo, Hyun Deog; Li, Yifei; Liang, Yanliang; Lan, Yucheng; Wang, Feng; Yao, Yan

doi:10.1002/cnma.201600117

Intercalation Pseudocapacitance of Exfoliated Molybdenum Disulfide for Ultrafast Energy Storage

Journal Article · Mon May 23 00:00:00 EDT 2016 · ChemNanoMat

DOI:https://doi.org/10.1002/cnma.201600117· OSTI ID:1347281

Yoo, Hyun Deog ^[1]; Li, Yifei ^[1]; Liang, Yanliang ^[1]; Lan, Yucheng ^[2]; Wang, Feng ^[3]; Yao, Yan ^[4]

University of Houston, TX (United States). Department of Electrical & Computer Engineering and Materials Science and Engineering Program
Morgan State University, Baltimore, MD (United States). Department of Physics and Engineering Physics
Brookhaven National Lab. (BNL), Upton, NY (United States). Sustainable Energy Technologies Department
University of Houston, TX (United States). Department of Electrical & Computer Engineering and Materials Science and Engineering Program and Texas Centre for Superconductivity

In this study, we report intercalation pseudocapacitance of 250 F g^-1 for exfoliated molybdenum disulfide (MoS₂) in non-aqueous electrolytes that contain lithium ions. The exfoliated MoS₂ shows surface-limited reaction kinetics with high rate capability up to 3 min of charge or discharge. The intercalation pseudocapacitance originates from the extremely fast kinetics due to the enhanced ionic and electronic transport enabled by the slightly expanded layer structure as well as the metallic 1T-phase. The exfoliated MoS₂ could be also used in a Li-Mg-ion hybrid capacitor, which shows full cell specific capacitance of 240 F g^-1.

View Accepted Manuscript (DOE)

Research Organization:: Brookhaven National Laboratory (BNL), Upton, NY (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE), Vehicle Technologies Office (EE-3V)

OSTI ID:: 1347281

Report Number(s):: BNL--112700-2016-JA

Journal Information:: ChemNanoMat, Journal Name: ChemNanoMat Journal Issue: 7 Vol. 2; ISSN 2199-692X

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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25 ENERGY STORAGE
36 MATERIALS SCIENCE
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Molybdenum disulphide
Supercapacitor

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