Transformation of 1,3-dioxacycloalkanes by the action of di-ethylaluminum hydride and triethylaluminum

Journal Article · Sat Nov 30 23:00:00 EST 1985 · J. Appl. Chem. USSR (Engl. Transl.); (United States)

OSTI ID:7150965

Volkov, A A; Kravets, E K; Rakhmankulov, D L; Zlot-skii, S S

The authors study the possibility of a selective hydrogenation of different 1,3-dioxacycloalkanes by industrial grade mixtures of diethylaluminum hydride and triethylaluminum. Experiments have shown that by the action of 0.4 mole of diethylaluminum hydride and 0.3 mole of triethylaluminum in 100 g of kerosene, 2-mono- and 2,2-disubstituted 2,3-dioxacycloalkanes selectively transform into the corresponding ethylene glycol monoethers. The PMR spectra of the isolated compounds are given. A Tesla BS-467 spectrometer, hexamethyldisiloxane as internal standard, and CC1/sub 4/ as solvent were used.

• OSTI ID: 7150965
• Journal Information: J. Appl. Chem. USSR (Engl. Transl.); (United States), Journal Name: J. Appl. Chem. USSR (Engl. Transl.); (United States) Vol. 58:7,PT.1; ISSN JAPUA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ALCOHOLS
ALKANES
ALKYL RADICALS
ALUMINIUM
ALUMINIUM COMPOUNDS
ALUMINIUM HYDRIDES
CATALYTIC EFFECTS
CHEMICAL REACTION YIELD
CHEMICAL REACTIONS
CHROMATOGRAPHY
CYCLOALKANES
ELECTRON SPIN RESONANCE
ELEMENTS
ETHYL RADICALS
GAS CHROMATOGRAPHY
GLYCOLS
HYDRIDES
HYDROCARBONS
HYDROGEN COMPOUNDS
HYDROGENATION
HYDROXY COMPOUNDS
MAGNETIC RESONANCE
METALS
ORGANIC COMPOUNDS
ORGANOMETALLIC COMPOUNDS
RADICALS
RESONANCE
SEPARATION PROCESSES
SPECTRA
YIELDS