Heteroadamantanes and their derivatives. 6. Synthesis and mass-spectrometric investigation of 5-mono- and 5,6-disubstituted 6-oxo-1,3-diazaadamantanes

Journal Article · Sun Jun 01 04:00:00 EDT 1986 · Chem. Heterocycl. Compd. (Engl. Transl.); (United States)

OSTI ID:6335248

Kuznetsov, A I; Basargin, E B; Moskovkin, A S; Ba, M Kh; Miroshnichenko, I V; Botnikov, M Ya; Unkovskii, B V

The corresponding 5-mono- and 5,7-disubstituted 6-oxo-1,3-diazaadamantanes were obtained with high yields by the condensation of mono- and ..cap alpha..,..cap alpha..'-disubstituted acetones with hexamethylenetetramine in the presence of glacial acetic acid, and their structures were confirmed by IR and PMR spectra. The behavior of the compounds under electron impact was studied, and the main fragmentation paths of their molecules were determined.

• Research Organization: M.V. Lomonosov Moscow Institute of Fine Chemical Technology, USSR
• OSTI ID: 6335248
• Journal Information: Chem. Heterocycl. Compd. (Engl. Transl.); (United States), Journal Name: Chem. Heterocycl. Compd. (Engl. Transl.); (United States) Vol. 21:12; ISSN CHCCA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
640304 -- Atomic
Molecular & Chemical Physics-- Collision Phenomena
74 ATOMIC AND MOLECULAR PHYSICS
ABSORPTION
ACETIC ACID
ACETONE
ADAMANTANE
ALKANES
AMINES
CARBOXYLIC ACIDS
CHARGED PARTICLES
CHEMICAL REACTION YIELD
CHEMICAL REACTIONS
COLLISIONS
CYCLOALKANES
DEHYDROCYCLIZATION
DIAZO COMPOUNDS
DISSOCIATION
ELECTRON COLLISIONS
ELECTRON-MOLECULE COLLISIONS
HETEROCYCLIC COMPOUNDS
HYDROCARBONS
INFRARED SPECTRA
IONIZATION
IONS
KETONES
MASS SPECTRA
MOLECULAR IONS
MOLECULAR STRUCTURE
MOLECULE COLLISIONS
MONOCARBOXYLIC ACIDS
MULTIPLETS
NMR SPECTRA
ORGANIC ACIDS
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
RESONANCE ABSORPTION
SPECTRA
STRUCTURAL CHEMICAL ANALYSIS
SYNTHESIS
YIELDS