Reaction of the rhodium hydridotrichlorostannyl complex (Bu/sub 4/N)/sub 3/(HRh(SnC1/sub 3/)/sub 5/) with tributylphosphine

Journal Article · Tue Oct 01 04:00:00 EDT 1985 · Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States)

DOI:https://doi.org/10.1007/BF00948070· OSTI ID:7150917

Krut'ko, D P; Permin, A B; Petrosyan, V S; Revtov, O A

In order to study the structures and reactivity of hydrido complexes of rhodium containing phosphine and halostannyl ligands simultaneously, the authors examine the reaction of (Bu/sub 4/N)/sub 3/(HRh(SnC1/sub 3/)/sub 5/)with tributylphosphine by P 31, H 1, and Sn 119 NMR. The reaction of tributylphosphine with the rhodium hydride was examined in CH/sub 2/C1/sub 2/, acetonitrile, and THF, which differ both in their polarities and in their solvating ability.

• Research Organization: M.V. Lomonosov Moscow State Univ
• OSTI ID: 7150917
• Journal Information: Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States), Journal Name: Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States) Vol. 34:4,PT. 2; ISSN BACCA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
CATALYSIS
CATALYTIC EFFECTS
CHEMICAL ANALYSIS
CHEMICAL REACTION KINETICS
CHEMICAL REACTION YIELD
COMPLEXES
DAYS LIVING RADIOISOTOPES
EVEN-ODD NUCLEI
HYDRIDES
HYDROGEN COMPOUNDS
INTERMEDIATE MASS NUCLEI
INTERNAL CONVERSION RADIOISOTOPES
ISOMERIC TRANSITION ISOTOPES
ISOTOPES
KINETICS
LIGANDS
LIGHT NUCLEI
NMR SPECTRA
NUCLEI
ODD-EVEN NUCLEI
PHOSPHINES
PHOSPHORUS 31
PHOSPHORUS COMPOUNDS
PHOSPHORUS ISOTOPES
PLATINUM COMPOUNDS
PLATINUM HYDRIDES
QUALITATIVE CHEMICAL ANALYSIS
RADIOISOTOPES
REACTION KINETICS
REACTIVITY
RHODIUM COMPLEXES
SPECTRA
STABLE ISOTOPES
TIN 119
TIN COMPLEXES
TIN ISOTOPES
TRANSITION ELEMENT COMPLEXES
TRANSITION ELEMENT COMPOUNDS
YIELDS