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Synthesis, NMR spectra, and structure of rhodium hydride complexes with Rh-Sn bonds

Journal Article · · Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States)
OSTI ID:5455337
; ; ;
The authors study the hydride complexes using Sn 119 and H 1 NMR spectroscopy. The spectra were taken in a pulse mode on a Varian FT-80A spectrometer equipped with a wideband system at 29.66 and 79.54 MHz. The Sn 119 and H 1 NMR spectral parameters for a solution of the complex (Bu/sub 4/N)/sub 3/ (HRh(SnCl/sub 3/)/sub 5/) in CD/sub 3/CN are shown, the spectra show that the (HRh(SnCl/sub 3/)/sub 5/)/sup 3 -/ anion has octahedral structure with four equatorial and one axial Rh-Sn bonds. New rhodium hydride complexes with general formula (R/sub 4/N)/sub 3/(HRh(SnCl/sub 3/)/sub 5/) were synthesized.
Research Organization:
M.V. Lomonosov Moscow State Univ.
OSTI ID:
5455337
Journal Information:
Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States), Journal Name: Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States) Vol. 33:12, PT. 2; ISSN BACCA
Country of Publication:
United States
Language:
English

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Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400301* -- Organic Chemistry-- Chemical & Physicochemical Properties-- (-1987)
ACETONITRILE
ALCOHOLS
ALKENES
CATALYTIC EFFECTS
CHEMICAL BONDS
CHEMICAL COMPOSITION
CHEMICAL REACTIONS
CHEMICAL SHIFT
CHLORIDES
CHLORINE COMPOUNDS
COMPLEXES
DAYS LIVING RADIOISOTOPES
DEHYDROGENATION
EVEN-ODD NUCLEI
HALIDES
HALOGEN COMPOUNDS
HYDRIDES
HYDROCARBONS
HYDROGEN 1
HYDROGEN COMPOUNDS
HYDROGEN ISOTOPES
HYDROXY COMPOUNDS
INTERMEDIATE MASS NUCLEI
INTERNAL CONVERSION RADIOISOTOPES
ISOMERIC TRANSITION ISOTOPES
ISOMERIZATION
ISOTOPES
LIGHT NUCLEI
MOLECULAR STRUCTURE
NITRILES
NMR SPECTRA
NUCLEI
ODD-EVEN NUCLEI
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
PRECIPITATION
RADIOISOTOPES
REFRACTORY METAL COMPOUNDS
RHODIUM COMPLEXES
RHODIUM COMPOUNDS
RHODIUM HYDRIDES
SEPARATION PROCESSES
SPECTRA
STABLE ISOTOPES
STRUCTURAL CHEMICAL ANALYSIS
TIN 119
TIN CHLORIDES
TIN COMPOUNDS
TIN HALIDES
TIN ISOTOPES
TRANSITION ELEMENT COMPLEXES
TRANSITION ELEMENT COMPOUNDS