Effects of polar aprotic solvents on the rate of the topochemical reaction of benzoyl chloride with sodium azide in o-xylene

Journal Article · Tue Oct 01 00:00:00 EDT 1985 · Kinet. Catal. (Engl. Transl.); (United States)

OSTI ID:7150832

Zlobin, V A

The kinetics of the topochemical reaction of benozyl chloride with sodium azide in o-xylene have been examined in the presence of varying amounts of acetonitrile and dimethylformamide. The specific rates and activation energies for the reaction have been found. These parameters have been found to increase with the amounts of polar aprotic solvent added. The observed dependence is explained by a change in the mechanism of the reaction.

• Research Organization: V.V. Kuibyshev Polytechnic Institute
• OSTI ID: 7150832
• Journal Information: Kinet. Catal. (Engl. Transl.); (United States), Journal Name: Kinet. Catal. (Engl. Transl.); (United States) Vol. 26:2,PT.2; ISSN KICAA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ACETONITRILE
ACTIVATION ENERGY
ALKALI METAL COMPOUNDS
ALKYLATED AROMATICS
AMIDES
AROMATICS
AZIDES
CATALYSIS
CATALYTIC EFFECTS
CHEMICAL REACTION KINETICS
ENERGY
FORMAMIDE
HETEROGENEOUS CATALYSIS
HYDROCARBONS
KINETICS
NITRILES
NITROGEN COMPOUNDS
ORGANIC CHLORINE COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
ORGANIC SOLVENTS
REACTION KINETICS
SODIUM COMPOUNDS
SOLVENT PROPERTIES
SOLVENTS
XYLENES