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Equilibrium constants of reactions of displacement of halogens by other halogens from molten chlorides, bromides, and iodides of alkali metals

Journal Article · · J. Appl. Chem. USSR (Engl. Transl.); (United States)
OSTI ID:7150590

In electrochemical experiments cases occur when a halogen (chlorine, bromine, or iodine) electrode is immersed in a melt consisting of a mixture of two halides with different anions rather than an individual alkali halide. During the operation of such electrodes the composition of the electrolyte may alter as the result of such displacement reactions. The authors use an independent method for determining equilibrium constants of all exchange reactions of chloride, bromine, and iodine with molten lithium, sodium, potassium, rubidium, and cesium chlorides, bromides, and iodides.

OSTI ID:
7150590
Journal Information:
J. Appl. Chem. USSR (Engl. Transl.); (United States), Journal Name: J. Appl. Chem. USSR (Engl. Transl.); (United States) Vol. 58:7,PT.2; ISSN JAPUA
Country of Publication:
United States
Language:
English