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Potential differences between chlorine and bromine electrode and between chlorine and iodine electrode in melts of the corresponding alkali-metal halides

Journal Article · · Sov. Electrochem. (Engl. Transl.); (United States)
OSTI ID:7059685
; ;

Halogen electrodes, according to the authors, are the most convenient electrodes for thermodynamic studies of reactions involving halogens in molten alkali metal halides when the emf method is used. The authors measured the potential differences between the chlorine and bromine electrode and between the chlorine and iodine electrode in cells described here. From the results of measurements at different temperatures, the authors generalized interpolation relations between the potentials of the bromine and iodine electrode in molten alkalimetal bromides and iodides and their mixtures relative to the chlorine electrode in chlorides of the same metals, on one hand, and the temperature and cation's crystal radius on the other hand.

Research Organization:
Institute of Electrochemistry, Ural Science Center, Academy of Sciences of the USSR, Sverdlovsk
OSTI ID:
7059685
Journal Information:
Sov. Electrochem. (Engl. Transl.); (United States), Journal Name: Sov. Electrochem. (Engl. Transl.); (United States) Vol. 21:12; ISSN SOECA
Country of Publication:
United States
Language:
English

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Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400400* -- Electrochemistry
ALKALI METAL COMPOUNDS
BROMIDES
BROMINE
BROMINE COMPOUNDS
CESIUM BROMIDES
CESIUM CHLORIDES
CESIUM COMPOUNDS
CESIUM IODIDES
CHLORIDES
CHLORINE
CHLORINE COMPOUNDS
ELECTRIC POTENTIAL
ELECTROCHEMICAL CELLS
ELECTRODES
ELECTROLYTES
ELECTROMOTIVE FORCE
ELEMENTS
HALIDES
HALOGEN COMPOUNDS
HALOGENS
INORGANIC PHOSPHORS
IODIDES
IODINE
IODINE COMPOUNDS
LITHIUM BROMIDES
LITHIUM CHLORIDES
LITHIUM COMPOUNDS
LITHIUM HALIDES
LITHIUM IODIDES
MOLTEN SALTS
NONMETALS
PHOSPHORS
POTASSIUM BROMIDES
POTASSIUM CHLORIDES
POTASSIUM COMPOUNDS
POTASSIUM IODIDES
RUBIDIUM BROMIDES
RUBIDIUM CHLORIDES
RUBIDIUM COMPOUNDS
RUBIDIUM IODIDES
SALTS
SODIUM BROMIDES
SODIUM CHLORIDES
SODIUM COMPOUNDS
SODIUM IODIDES
TEMPERATURE DEPENDENCE
THERMODYNAMICS