Carbon-hydrogen bond activation by electrophilic transition-metal compounds. Palladium(II)-mediated oxidation of arenes and alkanes including methane
Journal Article
·
· J. Am. Chem. Soc.; (United States)
The activation of carbon-hydrogen bonds by transition metals that leads to the selective functionalization of hydrocarbons, especially alkanes, is one of the most challenging problems in organometallic chemistry. Herein, the authors report on the palladium(II)-mediated oxidation of arenes and alkanes through a nonradical, electrophilic C-H activation pathway.
- Research Organization:
- Pennsylvania State Univ., University Park (USA)
- DOE Contract Number:
- FG02-84ER13295
- OSTI ID:
- 7148430
- Journal Information:
- J. Am. Chem. Soc.; (United States), Journal Name: J. Am. Chem. Soc.; (United States) Vol. 109:26; ISSN JACSA
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ACTIVATION ENERGY
ALKANES
AROMATICS
CARBON
CATALYSIS
CATALYSTS
CATALYTIC EFFECTS
CHEMICAL BONDS
CHEMICAL REACTIONS
DATA
ELEMENTS
ENERGY
EXPERIMENTAL DATA
HYDROCARBONS
HYDROGEN
INFORMATION
METALS
NONMETALS
NUMERICAL DATA
ORGANIC COMPOUNDS
OXIDATION
PALLADIUM
PLATINUM METALS
TRANSITION ELEMENTS
400201* -- Chemical & Physicochemical Properties
ACTIVATION ENERGY
ALKANES
AROMATICS
CARBON
CATALYSIS
CATALYSTS
CATALYTIC EFFECTS
CHEMICAL BONDS
CHEMICAL REACTIONS
DATA
ELEMENTS
ENERGY
EXPERIMENTAL DATA
HYDROCARBONS
HYDROGEN
INFORMATION
METALS
NONMETALS
NUMERICAL DATA
ORGANIC COMPOUNDS
OXIDATION
PALLADIUM
PLATINUM METALS
TRANSITION ELEMENTS