Organometallic chemistry of rhodium tetraphenylporphyrin derivatives: formyl, hydroxymethyl, and alkyl complexes

Journal Article · Wed Oct 22 00:00:00 EDT 1986 · Inorg. Chem.; (United States)

DOI:https://doi.org/10.1021/ic00242a042· OSTI ID:7129733

Wayland, B B; Van Voorhees, S L; Wilker, C

Organometallic reactivity patterns of the rhodium tetraphenylporphyrin derivatives Rh(TPP)(H), Rh(TPP)/sup -/, and (Rh(TPP))/sub 2/ are found to closely parallel those of the corresponding rhodium octaethylporphyrins species. Preparation and physical properties of the formyl, hydroxymethyl, and alkyl complexes of Rh(TPP) are described along with the photoinduced insertion of carbon monoxide into the Rh-CH/sub 3/ bond. Thermodynamic values for the reaction Rh(TPP)(H) + CO in equilibrium Rh(TPP)(CHO) in C/sub 6/D/sub 6/ are ..delta..H/sup 0/ = -42 kJ/mol and ..delta..S/sup 0/ = -89 +/- 15 J/(K mol).

• Research Organization: Univ. of Pennsylvania, Philadelphia
• DOE Contract Number: AC02-83ER13133
• OSTI ID: 7129733
• Journal Information: Inorg. Chem.; (United States), Journal Name: Inorg. Chem.; (United States) Vol. 25:22; ISSN INOCA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
400500 -- Photochemistry
CARBON COMPOUNDS
CARBON MONOXIDE
CARBON OXIDES
CARBOXYLIC ACIDS
CHALCOGENIDES
CHEMICAL PREPARATION
CHEMICAL REACTIONS
COMPLEXES
DATA
DECOMPOSITION
EXPERIMENTAL DATA
HETEROCYCLIC ACIDS
HETEROCYCLIC COMPOUNDS
INFORMATION
NUMERICAL DATA
ORGANIC ACIDS
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
ORGANOMETALLIC COMPOUNDS
OXIDES
OXYGEN COMPOUNDS
PHOTOCHEMICAL REACTIONS
PHOTOLYSIS
PHYSICAL PROPERTIES
PORPHYRINS
RHODIUM COMPLEXES
SYNTHESIS
THERMODYNAMIC PROPERTIES
TRANSITION ELEMENT COMPLEXES