Reactivity patterns of H{sub 2} and CO with a rhodium (II) salen derivative. Formation of hydride, formyl, and dimetal ketone complexes and rhodium reduction
- Univ. of Pennsylvania, Philadelphia, PA (United States)
A benzene soluble dimeric rhodium (II) salen derivative, [(ttbs)Rh]{sub 2}, with a weak Rh-Rh bond (13 kcal mol{sup -1}) reacts with H{sub 2} and CO to produce hydride, metalloketone, and formyl complexes, but reaction of (ttbs)Rh-H with CO also induces migration of H{sup +} from rhodium to the salen ligand to form a rhodium (I) dicarbonyl complex, (Httbs)Rh(CO){sub 2}. 16 refs., 2 figs.
- Sponsoring Organization:
- USDOE
- DOE Contract Number:
- FG02-86ER13615
- OSTI ID:
- 102772
- Journal Information:
- Organometallics, Journal Name: Organometallics Journal Issue: 9 Vol. 13; ISSN ORGND7; ISSN 0276-7333
- Country of Publication:
- United States
- Language:
- English
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