Isolation, structure, and magnetic properties of a novel mononuclear rhodium(II) complex
Journal Article
·
· Journal of the American Chemical Society; (USA)
- Michigan State Univ., East Lansing (USA)
Our current research interests is the coordination chemistry of solvated polynuclear metal cations, especially the recently reported rhodium(II,II) complex, (Rh{sub 2}(CH{sub 3}CH){sub 4})(F{sub 4}){sub 4}. In order to circumvent the problems associated with preparing and handling aqua species, we have developed a convenient synthesis for the CH{sub 3}CN derivative of RH{sub 2} (vide supra), a compound that allows easy access to other monomeric and polynuclear compounds of Rh(II). We now also report the synthesis of a pseudo-octahedral rhodium(II) monomer stabilized only by two bulky phosphine ligands.
- OSTI ID:
- 7075727
- Journal Information:
- Journal of the American Chemical Society; (USA), Journal Name: Journal of the American Chemical Society; (USA) Vol. 111:14; ISSN 0002-7863; ISSN JACSA
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
36 MATERIALS SCIENCE
360101* -- Metals & Alloys-- Preparation & Fabrication
360104 -- Metals & Alloys-- Physical Properties
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400200 -- Inorganic
Organic
& Physical Chemistry
CALCULATION METHODS
COMPLEXES
DATA
DATA ANALYSIS
EXPERIMENTAL DATA
INFORMATION
MAGNETIC PROPERTIES
MEASURING INSTRUMENTS
MEASURING METHODS
NUMERICAL DATA
ORGANIC COMPOUNDS
ORGANOMETALLIC COMPOUNDS
PHYSICAL PROPERTIES
RHODIUM COMPLEXES
SYNTHESIS
TRANSITION ELEMENT COMPLEXES
360101* -- Metals & Alloys-- Preparation & Fabrication
360104 -- Metals & Alloys-- Physical Properties
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400200 -- Inorganic
Organic
& Physical Chemistry
CALCULATION METHODS
COMPLEXES
DATA
DATA ANALYSIS
EXPERIMENTAL DATA
INFORMATION
MAGNETIC PROPERTIES
MEASURING INSTRUMENTS
MEASURING METHODS
NUMERICAL DATA
ORGANIC COMPOUNDS
ORGANOMETALLIC COMPOUNDS
PHYSICAL PROPERTIES
RHODIUM COMPLEXES
SYNTHESIS
TRANSITION ELEMENT COMPLEXES