Reactivity of various complex species of rhodium(III) in reactions with tin(II) chloride (in Russian)
Journal Article
·
· Sov. J. Coordinat. Chem.; (United States)
OSTI ID:6225920
The reactions of tin(II) chloride with monomeric chloroaquo, chloroammine, and nitro complexes, as well as polynuclear chloride, sulfate, and hydroxo compounds of rhodium(III), under standard conditions have been investigated. It has been shown that the formation of rhodium-tin chloride compounds is quantitative only for the chloroaquo and nitro complexes of rhodium(III). The reasons for the decrease in the reactivity of the other complex species have been analyzed. It has been concluded that the nature of the original complex of the inert metal has a decisive influence on the results of its analytical determination. The possibility of the application of the reaction with the tin(II) chloride to the analysis of rhodium compounds with organic ligands has been demonstrated.
- Research Organization:
- Novosibirsk State Univ., USSR
- OSTI ID:
- 6225920
- Journal Information:
- Sov. J. Coordinat. Chem.; (United States), Journal Name: Sov. J. Coordinat. Chem.; (United States) Vol. 11:3; ISSN SJCCD
- Country of Publication:
- United States
- Language:
- Russian
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Related Subjects
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ABSORPTION SPECTRA
ACTIVATION ENERGY
AMMINES
CALIBRATION
CATALYTIC EFFECTS
CHEMICAL ANALYSIS
CHEMICAL REACTION KINETICS
CHEMICAL REACTIONS
CHLORIDES
CHLORINE COMPOUNDS
COMPLEXES
COMPLEXOMETRY
DECOMPOSITION
ENERGY
HALIDES
HALOGEN COMPOUNDS
KINETICS
NITRO COMPOUNDS
ORGANIC CHLORINE COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
OXYGEN COMPOUNDS
QUANTITATIVE CHEMICAL ANALYSIS
REACTION KINETICS
REFRACTORY METAL COMPOUNDS
RHODIUM CHLORIDES
RHODIUM COMPLEXES
RHODIUM COMPOUNDS
SPECTRA
SULFATES
SULFUR COMPOUNDS
TIN CHLORIDES
TIN COMPOUNDS
TIN HALIDES
TRANSITION ELEMENT COMPLEXES
TRANSITION ELEMENT COMPOUNDS
400201* -- Chemical & Physicochemical Properties
ABSORPTION SPECTRA
ACTIVATION ENERGY
AMMINES
CALIBRATION
CATALYTIC EFFECTS
CHEMICAL ANALYSIS
CHEMICAL REACTION KINETICS
CHEMICAL REACTIONS
CHLORIDES
CHLORINE COMPOUNDS
COMPLEXES
COMPLEXOMETRY
DECOMPOSITION
ENERGY
HALIDES
HALOGEN COMPOUNDS
KINETICS
NITRO COMPOUNDS
ORGANIC CHLORINE COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
OXYGEN COMPOUNDS
QUANTITATIVE CHEMICAL ANALYSIS
REACTION KINETICS
REFRACTORY METAL COMPOUNDS
RHODIUM CHLORIDES
RHODIUM COMPLEXES
RHODIUM COMPOUNDS
SPECTRA
SULFATES
SULFUR COMPOUNDS
TIN CHLORIDES
TIN COMPOUNDS
TIN HALIDES
TRANSITION ELEMENT COMPLEXES
TRANSITION ELEMENT COMPOUNDS