The study of some transition metals complexes as process catalysts: Quarterly report for the period September 30, 1986 through November 30, 1986

Technical Report · Wed Jan 01 04:00:00 EST 1986

OSTI ID:7055582

Wilson, B L

During this past quarter, iron complexes with poly(pyrazolyl) borate ligands were prepared. Molybdenum complexes are under investigation by infrared and proton NMR. Cobalt complexes were fully characterized and tested as coal catalysts under various conditions. Nickel and iron complexes were evaluated along with FeCl/sub 3/ x 6H/sub 2/O, NiCl/sub 2/ x 6H/sub 2/O and potassium dihydrobis(pyrazolyl) borate as liquefaction catalysts. All of the above mentioned complexes have the poly(pyrazolyl) borate ligands. Table 5 lists and compares the data for various analytic liquefaction runs on Illinois Number Six River King coal with SRC-II distillate. 8 figs., 10 tabs.

• Research Organization: Texas Southern Univ., Houston (USA). Dept. of Chemistry
• DOE Contract Number: FG22-84PC70753
• OSTI ID: 7055582
• Report Number(s): DOE/PC/70753-T9; ON: DE87003423
• Country of Publication: United States
• Language: English

Related Subjects

01 COAL, LIGNITE, AND PEAT
010405* -- Coal
Lignite
& Peat-- Hydrogenation & Liquefaction
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201 -- Chemical & Physicochemical Properties
AUTOCLAVES
AZOLES
BORATES
BORON COMPOUNDS
CATALYSTS
CATALYTIC EFFECTS
CHEMICAL PREPARATION
CHLORIDES
CHLORINE COMPOUNDS
COAL LIQUEFACTION
COAL LIQUIDS
COMPARATIVE EVALUATIONS
COMPLEXES
DATA
DISTILLATES
EXPERIMENTAL DATA
FLUIDS
HALIDES
HALOGEN COMPOUNDS
HETEROCYCLIC COMPOUNDS
HIGH PRESSURE
HIGH TEMPERATURE
HYDRATES
INFORMATION
INFRARED SPECTRA
IRON CHLORIDES
IRON COMPLEXES
IRON COMPOUNDS
LIGANDS
LIQUEFACTION
LIQUIDS
MOLYBDENUM COMPLEXES
NICKEL CHLORIDES
NICKEL COMPLEXES
NICKEL COMPOUNDS
NMR SPECTRA
NUMERICAL DATA
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
OXYGEN COMPOUNDS
PERFORMANCE TESTING
PYRAZOLES
SPECTRA
SRC-II PROCESS
STRUCTURAL CHEMICAL ANALYSIS
SYNTHESIS
TESTING
THERMOCHEMICAL PROCESSES
TRANSITION ELEMENT COMPLEXES
TRANSITION ELEMENT COMPOUNDS