Study of some transition metal complexes as process catalysts. Quarterly report, June 1-August 31, 1986

Technical Report · Wed Jan 01 04:00:00 EST 1986

OSTI ID:5069836

Wilson, B L

During this past quarter, nickel, iron and molybdenum complexes with poly(pyrazolyl) borate ligands were prepared. Molybdenum complexes are under investigation by infrared and proton NMR. Cobalt, zinc and iron complexes were fully characterized and tested as coal liquefaction catalysts under various conditions. Melting point determinations were made for iron and nickel complexes and are reported in Table 1. Table 6 lists and compares the data for various catalytic liquefaction run on Illinois Number Six River King coal in the presence of SRC-II distillate. 3 figs., 6 tabs.

• Research Organization: Texas Southern Univ., Houston (USA). Dept. of Chemistry
• DOE Contract Number: FG22-84PC70753
• OSTI ID: 5069836
• Report Number(s): DOE/PC/70753-T8; ON: DE87000188
• Country of Publication: United States
• Language: English

Related Subjects

01 COAL, LIGNITE, AND PEAT
010405* -- Coal
Lignite
& Peat-- Hydrogenation & Liquefaction
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400301 -- Organic Chemistry-- Chemical & Physicochemical Properties-- (-1987)
AMMONIUM COMPOUNDS
AUTOCLAVES
AZOLES
BORATES
BORON COMPOUNDS
CATALYSTS
CATALYTIC EFFECTS
CHEMICAL PREPARATION
COAL LIQUEFACTION
COAL LIQUIDS
COBALT COMPLEXES
COMPARATIVE EVALUATIONS
COMPLEXES
DATA
DISTILLATES
EXPERIMENTAL DATA
FLUIDS
HETEROCYCLIC COMPOUNDS
HIGH PRESSURE
HIGH TEMPERATURE
INFORMATION
INFRARED SPECTRA
IRON COMPLEXES
LIGANDS
LIQUEFACTION
LIQUIDS
MEDIUM PRESSURE
MELTING POINTS
MOLYBDENUM COMPLEXES
NICKEL COMPLEXES
NMR SPECTRA
NUMERICAL DATA
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
OXYGEN COMPOUNDS
PERFORMANCE TESTING
PHYSICAL PROPERTIES
PYRAZOLES
RESEARCH PROGRAMS
SPECTRA
SRC-II PROCESS
STRUCTURAL CHEMICAL ANALYSIS
SYNTHESIS
TESTING
THERMOCHEMICAL PROCESSES
THERMODYNAMIC PROPERTIES
TRANSITION ELEMENT COMPLEXES
TRANSITION TEMPERATURE
YIELDS
ZINC COMPLEXES