Carbon number distribution and the chain-growth mechanism of products in the modified Fischer-Tropsch synthesis on a reduced promoted fused magnetite catalyst
Journal Article
·
· J. Catal.; (United States)
The investigation of carbon number distribution of FT synthesis products through the use of the well-known Schulz-Flory equations in the chemistry of polymers is the subject of numerous publications and is of interest in the study of the carbon chain-growth mechanism and the formation of synthesis products. To the authors, modified Fischer-Tropsch syntheses (CO + H/sub 2/ + substrate containing NH/sub 2/, OH, CHO, C=C, C similarly ordered C, and other groups) on iron catalysts are of particular interest in such studies. The present work is dedicated to the study of carbon number distribution of a real polyfunctional product of ammonia-modified FT synthesis. It discusses the mechanism of formation of alkylamines in this synthesis and of the chain-growth process. 10 references.
- Research Organization:
- Topchiev Institute of Petrochemical Synthesis, Moscow (USSR)
- OSTI ID:
- 7054831
- Journal Information:
- J. Catal.; (United States), Journal Name: J. Catal.; (United States) Vol. 111:2; ISSN JCTLA
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
01 COAL, LIGNITE, AND PEAT
010408* -- Coal
Lignite
& Peat-- C1 Processes-- (1987-)
ALKANES
ALKENES
AMINES
AMMONIA
CARBON COMPOUNDS
CARBON MONOXIDE
CARBON OXIDES
CATALYTIC EFFECTS
CHALCOGENIDES
CHEMICAL REACTION KINETICS
CHEMICAL REACTION YIELD
CHEMICAL REACTIONS
DISTRIBUTION
ELEMENTS
FISCHER-TROPSCH SYNTHESIS
HYDRIDES
HYDROCARBONS
HYDROGEN
HYDROGEN COMPOUNDS
IRON COMPOUNDS
IRON ORES
IRON OXIDES
KETONES
KINETICS
MAGNETITE
MINERALS
MOLECULAR WEIGHT
NITROGEN COMPOUNDS
NITROGEN HYDRIDES
NONMETALS
ORES
ORGANIC COMPOUNDS
OXIDE MINERALS
OXIDES
OXYGEN COMPOUNDS
REACTION KINETICS
TRANSITION ELEMENT COMPOUNDS
YIELDS
010408* -- Coal
Lignite
& Peat-- C1 Processes-- (1987-)
ALKANES
ALKENES
AMINES
AMMONIA
CARBON COMPOUNDS
CARBON MONOXIDE
CARBON OXIDES
CATALYTIC EFFECTS
CHALCOGENIDES
CHEMICAL REACTION KINETICS
CHEMICAL REACTION YIELD
CHEMICAL REACTIONS
DISTRIBUTION
ELEMENTS
FISCHER-TROPSCH SYNTHESIS
HYDRIDES
HYDROCARBONS
HYDROGEN
HYDROGEN COMPOUNDS
IRON COMPOUNDS
IRON ORES
IRON OXIDES
KETONES
KINETICS
MAGNETITE
MINERALS
MOLECULAR WEIGHT
NITROGEN COMPOUNDS
NITROGEN HYDRIDES
NONMETALS
ORES
ORGANIC COMPOUNDS
OXIDE MINERALS
OXIDES
OXYGEN COMPOUNDS
REACTION KINETICS
TRANSITION ELEMENT COMPOUNDS
YIELDS