The [nu][sub 1] + [nu][sub 3] bands of [sup 16]O[sup 18]O[sup 16]O and [sup 16]O[sup 16]O[sub 18]O

Journal Article · Wed Jun 01 04:00:00 EDT 1994 · Journal of Molecular Spectroscopy; (United States)

DOI:https://doi.org/10.1006/jmsp.1994.1149· OSTI ID:7036633

Flaud, J M; Camy-Peyret, C ^[1]; Bourgeois, M T; Barbe, A; Plateaux, J J ^[2]

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1. Univ. Pierre et Marie Curie, Paris (France). Lab. de Physique Moleculaire et Applications
2. Univ. de Reims (France). Groupe de Spectroscopie Moleculaire et Atmospherique

Using 0.003 cm[sup [minus]1] resolution fourier transform spectra of [sup 18]O-enriched ozone around 4.8 [mu]m, the first high-resolution analysis of the [nu][sub 1] + [nu][sub 3] bands of [sup 16]O[sup 18]O[sup 16]O and [sup 16]O[sup 16]O[sup 18]O has been performed. The experimental rotational energy levels were reproduced satisfactorily with the aid of a Hamiltonian model taking fully into account the vibration-rotation interactions. Indeed, it did not prove possible to fit properly the (101) levels without including in the Hamiltonian model both the Coriolis interactions coupling the levels of (101) with those of (002) and (200) and the Darling-Dennison interaction coupling the levels of (002) with those of (200). In this way reliable vibrational energies and rotational and coupling constants were deduced with the following band-centers: [nu][sub 0]([nu][sub 1] + [nu][sub 3]) = 2,049.3694 cm[sup [minus]1] for [sup 16]O[sup 18]O[sup 16]O, and [nu][sub 0]([nu][sub 1] + [nu][sub 3]) = 2,090.3406 cm[sup [minus]1] for [sup 16]O[sup 16]O[sup 18]O.

• OSTI ID: 7036633
• Journal Information: Journal of Molecular Spectroscopy; (United States), Journal Name: Journal of Molecular Spectroscopy; (United States) Vol. 165:2; ISSN JMOSA3; ISSN 0022-2852
• Country of Publication: United States
• Language: English

Related Subjects

54 ENVIRONMENTAL SCIENCES
540120* -- Environment
Atmospheric-- Chemicals Monitoring & Transport-- (1990-)
DATA
EARTH ATMOSPHERE
ENERGY LEVELS
EVEN-EVEN NUCLEI
EXCITED STATES
EXPERIMENTAL DATA
FOURIER TRANSFORM SPECTROMETERS
INFORMATION
ISOTOPES
LIGHT NUCLEI
MEASURING INSTRUMENTS
NUCLEI
NUMERICAL DATA
OXYGEN 16
OXYGEN 18
OXYGEN ISOTOPES
OZONE
ROTATIONAL STATES
SPECTROMETERS
STABLE ISOTOPES