Line positions and intensities of the [nu][sub 1] + 2[nu][sub 2] + [nu][sub 3] and 2[nu][sub 2] + 2[nu][sub 3] bands of [sup 16]O[sub 3]

Journal Article · Mon Aug 01 04:00:00 EDT 1994 · Journal of Molecular Spectroscopy; (United States)

DOI:https://doi.org/10.1006/jmsp.1994.1201· OSTI ID:7001343

Bouazza, S; Barbe, A; Mikhailenko, S; Plateaux, J J ^[1]

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1. URA CNRS, Reims (France). Groupe de Spectrometrie Moleculaire et Atmospherique

A study of high-resolution (0.006 cm[sup [minus]1]) Fourier transform absorption spectra of [sup 16]O[sub 3] around 3,450 cm[sup [minus]1] has been performed, leading to the first analysis of the [nu][sub 1] + 2[nu][sub 2] + [nu][sub 3] and 2[nu][sub 2] + 2[nu][sub 3] bands of this molecule. To increase the absorption strength of these very weak bands a White cell with path lengths of up to 36 m and pressures from 40 to 55 Torr was used. The rotational energy levels of the (121) and (022) vibrational states deduced from observed spectra have been satisfactorily reproduced using a Hamiltonian matrix which takes explicitly into account the Coriolis interaction between (121) [leftrightarrow] (022) and (121) [leftrightarrow] (220) and Darling-Dennison interaction between (022) [leftrightarrow] (220). Furthermore about 60 and 20 line intensities, respectively, for the (121) and (022) bands were measured with an accuracy of about 6 and 12%, leading to the determination of the [nu][sub 1] + 2[nu][sub 2] + [nu][sub 3] and 2[nu][sub 2] + 2[nu][sub 3] vibrational transition moments. Finally, a complete list of line positions, intensities, and lower state energies for both bands has been generated.

• OSTI ID: 7001343
• Journal Information: Journal of Molecular Spectroscopy; (United States), Journal Name: Journal of Molecular Spectroscopy; (United States) Vol. 166:2; ISSN JMOSA3; ISSN 0022-2852
• Country of Publication: United States
• Language: English

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540120* -- Environment
Atmospheric-- Chemicals Monitoring & Transport-- (1990-)
ABSORPTION SPECTRA
ENERGY LEVELS
EVEN-EVEN NUCLEI
EXCITED STATES
FOURIER TRANSFORMATION
INTEGRAL TRANSFORMATIONS
ISOTOPES
LIGHT NUCLEI
NUCLEI
OXYGEN 16
OXYGEN ISOTOPES
OZONE
SPECTRA
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TRANSFORMATIONS
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