A novel process for methanol synthesis. [Concurrent sythesis of methly formate and methanol]

Technical Report · Wed Jan 01 00:00:00 EST 1992

DOI:https://doi.org/10.2172/7025962· OSTI ID:7025962

Tierney, J W; Wender, I

A bench-scale reactor is being used to conduct studies of the conversion of synthesis gas to methanol (MeOH) by a novel process. In previous reports, we provided evidence for a two-step reaction in series, the carbonylation reaction taking place mainly in a non-equilibrium region in the vicinity of the copper chromite surface, and the hydrogenolysis reaction taking place on the surface of the copper chromite. Interaction between the two catalysts enhances the rate of methanol formation. In this quarter, we investigated the effect of pore diffusion on reaction rate and obtained an expression for the rate of reaction for the methanol/methyl formate concurrent synthesis.

• Research Organization: Pittsburgh Univ., PA (United States). Dept. of Chemical and Petroleum Engineering
• Sponsoring Organization: USDOE; USDOE, Washington, DC (United States)
• DOE Contract Number: FG22-89PC89786
• OSTI ID: 7025962
• Report Number(s): DOE/PC/89786-T13; ON: DE92019719
• Country of Publication: United States
• Language: English

Related Subjects

01 COAL, LIGNITE, AND PEAT
10 SYNTHETIC FUELS
CARBOXYLIC ACID ESTERS
SYNTHESIS
CHROMIUM COMPOUNDS
CATALYTIC EFFECTS
COPPER COMPOUNDS
METHANOL
SYNTHESIS GAS
CONVERSION
BENCH-SCALE EXPERIMENTS
CARBONYLATION
CHEMICAL REACTION KINETICS
CHEMICAL REACTORS
HYDROGENATION
PROGRESS REPORT
REACTION INTERMEDIATES
ALCOHOLS
CHEMICAL REACTIONS
DOCUMENT TYPES
ESTERS
FLUIDS
GASES
HYDROXY COMPOUNDS
KINETICS
ORGANIC COMPOUNDS
REACTION KINETICS
TRANSITION ELEMENT COMPOUNDS
010408* - Coal
Lignite
& Peat- C1 Processes- (1987-)
100200 - Synthetic Fuels- Production- (1990-)