A novel process for methanol synthesis. Progress report, March 1, 1992--May 31, 1992

Technical Report · Tue Sep 01 00:00:00 EDT 1992

DOI:https://doi.org/10.2172/10174279· OSTI ID:10174279

Tierney, J W; Wender, I

A bench-scale reactor is being used to conduct studies of the conversion of synthesis gas to methanol (MeOH) by a novel process. In previous reports, we provided evidence for a two-step reaction in series, the carbonylation reaction taking place mainly in a non-equilibrium region in the vicinity of the copper chromite surface, and the hydrogenolysis reaction taking place on the surface of the copper chromite. Interaction between the two catalysts enhances the rate of methanol formation. In this quarter, we investigated the effect of pore diffusion on reaction rate and obtained an expression for the rate of reaction for the methanol/methyl formate concurrent synthesis.

• Research Organization: Pittsburgh Univ., PA (United States). Dept. of Chemical and Petroleum Engineering
• Sponsoring Organization: USDOE, Washington, DC (United States)
• DOE Contract Number: FG22-89PC89786
• OSTI ID: 10174279
• Report Number(s): DOE/PC/89786--T13; ON: DE92019719
• Country of Publication: United States
• Language: English

Related Subjects

01 COAL, LIGNITE, AND PEAT
010408
10 SYNTHETIC FUELS
100200
BENCH-SCALE EXPERIMENTS
C1 PROCESSES
CARBONYLATION
CARBOXYLIC ACID ESTERS
CATALYTIC EFFECTS
CHEMICAL REACTION KINETICS
CHEMICAL REACTORS
CHROMIUM COMPOUNDS
CONVERSION
COPPER COMPOUNDS
HYDROGENATION
METHANOL
PRODUCTION
PROGRESS REPORT
REACTION INTERMEDIATES
SYNTHESIS
SYNTHESIS GAS