Application of solid polymer electrolyte to lithium/polypyrrole secondary battery system
- Waseda Univ., Tokyo (Japan). Dept. of Applied Chemistry
An all solid-state lithium/polypyrrole (PPy) battery using polyethylene oxide (PEO)-LiClO[sub 4] as a solid polymer electrolyte was assembled, and the effects of the morphology of the PPy film and the concentration of LiClO[sub 4] on battery performance were investigated. Optimum conditions for the redox properties of PPy films in PEO-LiClO[sub 4] at 80 C were obtained with an LiClO[sub 4] concentration of n = 8 [approximately] 20 (n=[EO]/[Li]) when using rough PPy film. A Li/PPy battery using PEO-LiClO[sub 4] with optimized conditions exhibited high coulombic efficiency, above 90% at 0.1 mA cm [sup [minus]2] at 80 C. Cyclability of 1,400 cycles with high coulombic efficiency was attained.
- OSTI ID:
- 7023925
- Journal Information:
- Journal of the Electrochemical Society; (United States), Journal Name: Journal of the Electrochemical Society; (United States) Vol. 141:8; ISSN JESOAN; ISSN 0013-4651
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
250902* -- Energy Storage-- Batteries-- Performance & Testing
250903 -- Energy Storage-- Batteries-- Materials
Components
& Auxiliaries
ALKALI METAL COMPOUNDS
AZOLES
BATTERY CHARGING
CHEMICAL REACTIONS
CHLORATES
CHLORINE COMPOUNDS
EFFICIENCY
ELECTRIC BATTERIES
ELECTROCHEMICAL CELLS
ELECTROLYTES
ENERGY EFFICIENCY
HALOGEN COMPOUNDS
HETEROCYCLIC COMPOUNDS
LITHIUM COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
OXYGEN COMPOUNDS
PERFORMANCE
PYRROLES
REDOX REACTIONS
SOLID ELECTROLYTES
VOLTAGE DROP