All-solid-state electric double-layer capacitor with isotropic high-density graphite electrode and polyethylene oxide/LiClO{sub 43} polymer electrolyte
Journal Article
·
· Journal of the Electrochemical Society
- Waseda Univ., Tokyo (Japan)
An isotropic high-density graphite was used as a polarizable electrode of all-solid state electric double-layer capacitor using polyethylene oxide (PEO) or gel PEO electrolyte. The all-solid-state capacitor with high-density graphite electrodes possesses higher differential capacity than the other flat electrodes in PEO/LiClO{sub 4} ([EO]/[Li{sup +}] = 8:1) solid polymer electrolyte at 80 C or PEO/PC/LiClO{sub 4} ([EO]/[PC]/[Li{sup +}] = 8:8:1) gel electrolyte at ambient temperature. The capacitance of the electric double layer of the high-density graphite electrode was strongly influenced by the cell temperature and concentration of LiClO{sub 4}, because of the different state of the polymer crystallinity and different interface contact state between the high-density graphite electrode and the solid electrolyte. The all-solid-state capacitor with PEO/LiClO{sub 4} ([EO]/[Li{sup +}] = 8:1) solid polymer electrolyte and PEO/PC/LiClO{sub 4} ([EO]/[PC]/[Li{sup +}] = 8:8:1) gel electrolytes showed good charge/discharge behavior with a relatively high capacitance at 80 and 20 C, respectively.
- Sponsoring Organization:
- USDOE
- OSTI ID:
- 474630
- Journal Information:
- Journal of the Electrochemical Society, Journal Name: Journal of the Electrochemical Society Journal Issue: 12 Vol. 143; ISSN 0013-4651; ISSN JESOAN
- Country of Publication:
- United States
- Language:
- English
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