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Structure of low-temperature IR absorption spectra of KCl and KBr crystals with NO/sub 2/- and NO/sub 3/- anion impurities

Journal Article · · J. Appl. Spectrosc. (Engl. Transl.); (United States)
OSTI ID:7008763
; ; ;
The vibrational and hyperfine structure of the infrared absorption spectra of KCl and KBr crystals doped with the molecular monovalent anions of nitrogen dioxide and nitrogen trioxide and additionally doped or not doped with divalent cations of calcium and barium is analyzed at a temperature of 4.2 K in this paper. The penetration of the ions into the crystal lattices and their complexing behavior with the halides are determined. The isotopic structure of the infrared spectra is also analyzed for nitrogen dioxide and trioxide anions comprised of nitrogen 14/oxygen 16, nitrogen 15/oxygen 16, nitrogen 14/oxygen 18, and nitrogen 14/oxygen 16/oxygen 18 isotope compositions.
OSTI ID:
7008763
Journal Information:
J. Appl. Spectrosc. (Engl. Transl.); (United States), Journal Name: J. Appl. Spectrosc. (Engl. Transl.); (United States) Vol. 46:5; ISSN JASYA
Country of Publication:
United States
Language:
English

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Related Subjects

36 MATERIALS SCIENCE
360602* -- Other Materials-- Structure & Phase Studies
360603 -- Materials-- Properties
640302 -- Atomic
Molecular & Chemical Physics-- Atomic & Molecular Properties & Theory
74 ATOMIC AND MOLECULAR PHYSICS
ABSORPTION SPECTRA
ALKALI METAL COMPOUNDS
ALKALINE EARTH METAL COMPOUNDS
ANIONS
BARIUM COMPOUNDS
BINDING ENERGY
BROMIDES
BROMINE COMPOUNDS
CALCIUM COMPOUNDS
CATIONS
CHARGED PARTICLES
CHLORIDES
CHLORINE COMPOUNDS
COMPLEXOMETRY
CRYSTAL DOPING
CRYSTAL LATTICES
CRYSTAL STRUCTURE
DIFFUSION
ENERGY
ENERGY LEVELS
EVEN-EVEN NUCLEI
EXCITED STATES
HALIDES
HALOGEN COMPOUNDS
HYPERFINE STRUCTURE
ION IMPLANTATION
IONS
ISOTOPE RATIO
ISOTOPES
LIGHT NUCLEI
LINE WIDTHS
NITRATES
NITROGEN 14
NITROGEN 15
NITROGEN COMPOUNDS
NITROGEN ISOTOPES
NUCLEI
ODD-EVEN NUCLEI
ODD-ODD NUCLEI
OXYGEN 16
OXYGEN 18
OXYGEN COMPOUNDS
OXYGEN ISOTOPES
POTASSIUM BROMIDES
POTASSIUM CHLORIDES
POTASSIUM COMPOUNDS
SPECTRA
STABLE ISOTOPES
ULTRALOW TEMPERATURE
VALENCE
VIBRATIONAL STATES