Amination of butanol on Na forms of zeolites

Journal Article · Tue Jun 10 00:00:00 EDT 1986 · Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States)

OSTI ID:7005841

Minachev, Kh M; Levitskii, I I; Maksimov, A I; Mishin, I V

This paper studies the amination of 1-butanol by ammonia on the forms of zeolites with a different SiO/sub 2//A1/sub 2/O/sub 3/ ratio and a different backbone structure. The catalytic properties of the zeolites were compared with A1/sub 2/O/sub 3/ which is a well-known catalyst of amination. It is shown that the activity and selectivity of the zeolites increase in the order na-mordenite NaA, NaHSZ, NaY, NaX. Nonlocalized sodium cations are the carriers of the catalytic activity in the reaction of amination on Na forms of zeolites.

• Research Organization: N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow
• OSTI ID: 7005841
• Journal Information: Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States), Journal Name: Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States) Vol. 34:12; ISSN BACCA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ALCOHOLS
ALKALI METAL COMPOUNDS
ALUMINIUM COMPOUNDS
ALUMINIUM OXIDES
AMINATION
AMINES
AMMONIA
BUTANOLS
CATALYTIC EFFECTS
CHALCOGENIDES
CHEMICAL COMPOSITION
CHEMICAL REACTION YIELD
CHEMICAL REACTIONS
COMPARATIVE EVALUATIONS
HYDRIDES
HYDROGEN COMPOUNDS
HYDROXY COMPOUNDS
INORGANIC ION EXCHANGERS
ION EXCHANGE MATERIALS
MATERIALS
MATERIALS TESTING
MINERALS
NITROGEN COMPOUNDS
NITROGEN HYDRIDES
ORGANIC COMPOUNDS
OXIDES
OXYGEN COMPOUNDS
QUANTITY RATIO
SILICON COMPOUNDS
SILICON OXIDES
SODIUM COMPOUNDS
TESTING
YIELDS
ZEOLITES