Dehydration of 3-methyl-2-butanol on zeolites

Journal Article · Mon Aug 10 00:00:00 EDT 1987 · Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States)

DOI:https://doi.org/10.1007/BF00959354· OSTI ID:5675801

Levitskii, I I; Maksimov, A I; Mishin, I V; Minachev, K M

Dehydration of 3-methyl-2-butanol on zeolites Y, mordenite, and entasil in the sodium and hydrogen forms and on dealuminated mordenites was studied. The hydrogen forms of zeolites from the pentasil family and dealuminated mordenite with a SiO/sub 2//Al/sub 2/O/sub 3/ ratio of 14 exhibit the highest activity. 3-Methyl-2-butanol is dehydrated on the zeolites not only according to the mechanism of ..beta..-elimination, but also according to the mechanism of ..gamma..-elimination to a significant degree.

• Research Organization: N.D. Zelinskii Institute of Organic Chemistry, Moscow, USSR
• OSTI ID: 5675801
• Journal Information: Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States), Journal Name: Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States) Vol. 36:2; ISSN BACCA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ALCOHOLS
ALKENES
BUTANOLS
CATALYSIS
CATALYTIC EFFECTS
CHEMICAL REACTION KINETICS
CHEMICAL REACTION YIELD
COMPARATIVE EVALUATIONS
DEHYDRATION
ELECTRON DENSITY
ELECTRON TRANSFER
HETEROGENEOUS CATALYSIS
HYDROCARBONS
HYDROXY COMPOUNDS
INORGANIC ION EXCHANGERS
ION EXCHANGE MATERIALS
KINETICS
MATERIALS
MINERALS
MORDENITE
ORGANIC COMPOUNDS
REACTION KINETICS
SILICATE MINERALS
TEMPERATURE DEPENDENCE
YIELDS
ZEOLITES