Influence of certain factors on catalytic oxidation of isopropylbenzene
Journal Article
·
· J. Appl. Chem. USSR (Engl. Transl.); (United States)
OSTI ID:6968431
This paper examines the influence of the catalyst concentration and temperature on the oxidation kinetics and also on the yield of the end product cumenyl hydroperoxide (CHP). It is shown that the catalytic activity of salt catalysis in oxidation of isopropylbenzene depends on their influence on decomposition of the hydroperoxide. The influence of temperature on the kinetics of accumulation of hydroperoxide oxygen-containing products of isopropylbenzene (IPB) oxidation was studied in the presence of zinc and cadmium naphthenates in 1 X 10/sup -3/ M concentration at temperatures in the range 100-140 degrees.
- Research Organization:
- All-Union Sci-Res. Institute of Petrochemical Processes
- OSTI ID:
- 6968431
- Journal Information:
- J. Appl. Chem. USSR (Engl. Transl.); (United States), Journal Name: J. Appl. Chem. USSR (Engl. Transl.); (United States) Vol. 59:1, PT. 2; ISSN JAPUA
- Country of Publication:
- United States
- Language:
- English
Similar Records
Kinetics of isopropylbenzene oxidation in presence of the catalytic system zinc naphthenate-1,10-phenanthroline
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Influence of the nature of the catalyst on the kinetics of accumulation of the products of cumenyl hydroperoxide decomposition in isopropylbenzene
Journal Article
·
Tue Dec 09 23:00:00 EST 1986
· J. Appl. Chem. USSR (Engl. Transl.); (United States)
·
OSTI ID:6294113
Catalysts for isopropylbenzene oxidation, activated by a conjugated heterocyclic ligand, 1,10-phenanthroline
Journal Article
·
Fri Aug 01 00:00:00 EDT 1986
· J. Appl. Chem. USSR (Engl. Transl.); (United States)
·
OSTI ID:7066437
Influence of the nature of the catalyst on the kinetics of accumulation of the products of cumenyl hydroperoxide decomposition in isopropylbenzene
Journal Article
·
Tue Dec 09 23:00:00 EST 1986
· J. Appl. Chem. USSR (Engl. Transl.); (United States)
·
OSTI ID:6294121
Related Subjects
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ALKANES
AROMATICS
CADMIUM COMPOUNDS
CATALYTIC EFFECTS
CHEMICAL REACTION KINETICS
CHEMICAL REACTION YIELD
CHEMICAL REACTIONS
CHROMATOGRAPHY
CUMENE
CYCLOALKANES
HYDROCARBONS
KINETICS
ORGANIC COMPOUNDS
ORGANOMETALLIC COMPOUNDS
OXIDATION
OXYGEN COMPOUNDS
PEROXIDES
REACTION KINETICS
SEPARATION PROCESSES
TEMPERATURE EFFECTS
YIELDS
ZINC COMPOUNDS
400201* -- Chemical & Physicochemical Properties
ALKANES
AROMATICS
CADMIUM COMPOUNDS
CATALYTIC EFFECTS
CHEMICAL REACTION KINETICS
CHEMICAL REACTION YIELD
CHEMICAL REACTIONS
CHROMATOGRAPHY
CUMENE
CYCLOALKANES
HYDROCARBONS
KINETICS
ORGANIC COMPOUNDS
ORGANOMETALLIC COMPOUNDS
OXIDATION
OXYGEN COMPOUNDS
PEROXIDES
REACTION KINETICS
SEPARATION PROCESSES
TEMPERATURE EFFECTS
YIELDS
ZINC COMPOUNDS