Comparison of adsorption parameters in different isotherms

Journal Article · Thu Oct 01 04:00:00 EDT 1987 · Sov. Electrochem. (Engl. Transl.); (United States)

OSTI ID:6961645

Past, U; Alumaa, A; Palm, U

The aim of this paper is to provide a method of interconversion for the adsorption isotherm parameters of organic compounds in different solvents and to propose a unified and rational scale for the standard free energies of adsorption under conditions including electrocatalysis. The method is tested against experimental data for the isotherms and heats of adsorption of naphthalene, hexadecane, and propyl, butyl, amyl, hexyl, and heptyl alcohols from water, methanol, and ethanol on remelted bismuth electrodes.

• Research Organization: Tartu State Univ. (USSR)
• OSTI ID: 6961645
• Journal Information: Sov. Electrochem. (Engl. Transl.); (United States), Journal Name: Sov. Electrochem. (Engl. Transl.); (United States) Vol. 23:4; ISSN SOECA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
400400 -- Electrochemistry
ADSORBENTS
ADSORPTION HEAT
ADSORPTION ISOTHERMS
ALCOHOLS
ALKANES
AROMATICS
BISMUTH
CATALYSIS
CATALYSTS
CATALYTIC EFFECTS
COMPARATIVE EVALUATIONS
CONDENSED AROMATICS
ELECTROCATALYSTS
ELEMENTS
ENTHALPY
EQUATIONS
ETHANOL
HETEROGENEOUS CATALYSIS
HEXADECANE
HYDROCARBONS
HYDROGEN COMPOUNDS
HYDROXY COMPOUNDS
ISOTHERMS
MATHEMATICAL MODELS
METALS
METHANOL
NAPHTHALENE
ORGANIC COMPOUNDS
ORGANIC SOLVENTS
OXYGEN COMPOUNDS
PHYSICAL PROPERTIES
SOLVENTS
SORPTIVE PROPERTIES
SURFACE PROPERTIES
THERMODYNAMIC PROPERTIES
VIRIAL EQUATION
WATER