Adsorption of certain surface-active organic substances on lead, and their effect on hydrogen evolution kinetics in sulfuric acid

Journal Article · Mon Feb 01 04:00:00 EST 1988 · Sov. Electrochem. (Engl. Transl.); (United States)

OSTI ID:6376538

Sherstobitova, I N; Iskhakov, R N

The adsorption of tetrabutylammonium sulfate, n-butyl, n-amyl, isoamyl, n-hexyl alcohol, butyric acid, butylamine, antipyrine and diantipyrylmethane was measured by differential-capacitance at a frequency of 10 kHz at smooth lead electrodes under cathodic polarization. Isotherms were determined by logarithms. Parameters in the Frumkin equation for adsorption of certain organic substances on lead were also determined and tabulated.

• Research Organization: A. M. Gorki State Univ., Perm (USSR)
• OSTI ID: 6376538
• Journal Information: Sov. Electrochem. (Engl. Transl.); (United States), Journal Name: Sov. Electrochem. (Engl. Transl.); (United States) Vol. 23:8; ISSN SOECA
• Country of Publication: United States
• Language: English

Related Subjects

08 HYDROGEN
080101* -- Hydrogen-- Production-- Electrolysis
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400400 -- Electrochemistry
ADSORPTION
ADSORPTION ISOTHERMS
ALCOHOLS
AMINES
AMMONIUM COMPOUNDS
AMMONIUM SULFATES
ANTIPYRETICS
ANTIPYRINE
AZOLES
BUTANOLS
BUTYRIC ACID
CAPACITANCE
CARBOXYLIC ACIDS
CATALYSTS
CATALYTIC EFFECTS
CENTRAL NERVOUS SYSTEM DEPRESSANTS
DRUGS
ELECTRICAL PROPERTIES
ELECTROCATALYSTS
ELECTRODES
ELECTROLYSIS
ELEMENTS
HETEROCYCLIC COMPOUNDS
HEXANOLS
HYDROGEN COMPOUNDS
HYDROGEN PRODUCTION
HYDROXY COMPOUNDS
INORGANIC ACIDS
ISOTHERMS
LEAD
LYSIS
METALS
MONOCARBOXYLIC ACIDS
ORGANIC ACIDS
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
OXYGEN COMPOUNDS
PENTANOLS
PHYSICAL PROPERTIES
POLARIZATION
PYRAZOLES
PYRAZOLINES
QUATERNARY COMPOUNDS
SORPTION
SORPTIVE PROPERTIES
SULFATES
SULFUR COMPOUNDS
SULFURIC ACID
SURFACE PROPERTIES
SURFACTANTS