Kinetic energy and temperature dependences of the rate constants for electron detachment of NO sup minus by N sub 2 O, CO sub 2 , N sub 2 , CH sub 4 , C sub 2 H sub 6 , and C sub 3 h sub 8

Journal Article · Thu Apr 19 00:00:00 EDT 1990 · Journal of Physical Chemistry; (USA)

DOI:https://doi.org/10.1021/j100371a014· OSTI ID:6945537

Viggiano, A A; Morris, R A; Paulson, J F ^[1]

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1. Ionospheric Physics Div., Hanscom Air Force Base, MA (USA)

Rate constants were measured as a function of average center-of-mass kinetic energy, , at several temperatures for the reactions of NO{sup {minus}} with N{sub 2}O, CO{sub 2}, C{sub 2}H{sub 6}, and C{sub 3}H{sub 8}. In addition, temperature dependences were measured for the rate constants of the reactions of NO{sup {minus}} with N{sub 2} and CH{sub 4}. In the reactions of C{sub 2}H{sub 6}, C{sub 3}H{sub 8}, N{sub 2}, and CH{sub 4}, the only channel observed was electron detachment. N{sub 2}O and CO{sub 2} reacted both by electron detachment and, at low temperature and low , by association.

• OSTI ID: 6945537
• Journal Information: Journal of Physical Chemistry; (USA), Journal Name: Journal of Physical Chemistry; (USA) Vol. 94:8; ISSN 0022-3654; ISSN JPCHA
• Country of Publication: United States
• Language: English

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