Reductive coupling of carbon monoxide to C sub 2 products
Progress since the initiation of this two year award on May 1, 1988, has been divided into two areas for reporting purposes. We have been working on ideas described in the proposal submitted two years ago, and simultaneously we initiated chemistry in a distinct area in order to provide a springboard for the current proposal. Efforts directed toward reductive coupling of carbon monoxide have continued to focus on carbyne species as the central figure in coupling reactions. At the same time we have attempted to prepare intermediate oxidation state metal imido complexes with an eye to synthetic applications of nitrene transfer reagents. The results of carbyne chemistry, electrophilic addition reactions of anionic carbonyl and isonitrile complexes, and carbyne-carbonyl coupling reactions will be presented in this progress report, while the work with nitrene complexes will be included as preliminary results in the text of the accompanying proposal. The description of published work will be brief in this report; greater detail will be provided for unpublished material.
- Research Organization:
- North Carolina Univ., Chapel Hill, NC (USA). Dept. of Chemistry
- Sponsoring Organization:
- DOE/ER
- DOE Contract Number:
- FG05-85ER13430
- OSTI ID:
- 6945205
- Report Number(s):
- DOE/ER/13430-5; ON: DE90011842
- Country of Publication:
- United States
- Language:
- English
Similar Records
Reductive coupling of carbon monoxide to C{sub 2} products. Progress report for the period, May 1, 1990--November 15, 1993
Tungsten nitrene complexes Tp prime W(CO) sub 2 (NR) sup + (R = Ph, Bu sup t ) generated from amido complexes Tp prime W(CO) sub 2 (NHR)
Reductive coupling of carbon monoxide to C sub 2 products
Technical Report
·
Fri Oct 01 00:00:00 EDT 1993
·
OSTI ID:10139407
Tungsten nitrene complexes Tp prime W(CO) sub 2 (NR) sup + (R = Ph, Bu sup t ) generated from amido complexes Tp prime W(CO) sub 2 (NHR)
Journal Article
·
Wed Oct 24 00:00:00 EDT 1990
· Journal of the American Chemical Society; (USA)
·
OSTI ID:6347431
Reductive coupling of carbon monoxide to C sub 2 products
Technical Report
·
Thu Aug 01 00:00:00 EDT 1991
·
OSTI ID:5764454
Related Subjects
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ALKYNES
CARBON COMPOUNDS
CARBON MONOXIDE
CARBON OXIDES
CARBYNES
CHALCOGENIDES
CHEMICAL PREPARATION
CHEMICAL REACTIONS
COMPLEXES
DOCUMENT TYPES
HYDRIDES
HYDROCARBONS
HYDROGEN COMPOUNDS
LIGANDS
ORGANIC COMPOUNDS
OXIDES
OXYGEN COMPOUNDS
PROGRESS REPORT
RADICALS
REFRACTORY METAL COMPOUNDS
SYNTHESIS
TANTALUM COMPLEXES
TRANSITION ELEMENT COMPLEXES
TRANSITION ELEMENT COMPOUNDS
TUNGSTEN COMPLEXES
TUNGSTEN COMPOUNDS
TUNGSTEN HYDRIDES
400201* -- Chemical & Physicochemical Properties
ALKYNES
CARBON COMPOUNDS
CARBON MONOXIDE
CARBON OXIDES
CARBYNES
CHALCOGENIDES
CHEMICAL PREPARATION
CHEMICAL REACTIONS
COMPLEXES
DOCUMENT TYPES
HYDRIDES
HYDROCARBONS
HYDROGEN COMPOUNDS
LIGANDS
ORGANIC COMPOUNDS
OXIDES
OXYGEN COMPOUNDS
PROGRESS REPORT
RADICALS
REFRACTORY METAL COMPOUNDS
SYNTHESIS
TANTALUM COMPLEXES
TRANSITION ELEMENT COMPLEXES
TRANSITION ELEMENT COMPOUNDS
TUNGSTEN COMPLEXES
TUNGSTEN COMPOUNDS
TUNGSTEN HYDRIDES