The study of ethane dehydrogenation in a catalytic membrane reactor

Journal Article · Tue Mar 31 23:00:00 EST 1992 · Journal of Catalysis; (United States)

DOI:https://doi.org/10.1016/0021-9517(92)90355-L· OSTI ID:6938874

Champagnie, A M; Tsotsis, T T; Minet, R G ^[1]; Wagner, E ^[2]

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1. Univ. of Southern California, Los Angeles (United States)
2. Kinetic Technology International, Inc., Monrovia, CA (United States)

Membrane reactors have the capability of combining reaction and separation in a single unit operation. The membrane selectively removes one or more product species. For a number of reactions, whose yields are limited by thermodynamic equilibrium, this results in an increase in the reactor conversion and a corresponding increase in product yields. One such reaction is the catalytic dehydrogenation of ethane. This reaction was studied in an isothermal high-temperature shell-and-tube membrane reactor, containing an alumina ceramic membrane tube impregnated with platinum. A theoretical model was developed for this reactor, based on isothermal conditions and plug-flow behavior. The model shows reasonable agreement with the experimental data.

• OSTI ID: 6938874
• Journal Information: Journal of Catalysis; (United States), Journal Name: Journal of Catalysis; (United States) Vol. 134:2; ISSN 0021-9517; ISSN JCTLA5
• Country of Publication: United States
• Language: English

Related Subjects

02 PETROLEUM
020400* -- Petroleum-- Processing
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201 -- Chemical & Physicochemical Properties
ALKANES
ALUMINIUM COMPOUNDS
ALUMINIUM OXIDES
CHALCOGENIDES
CHEMICAL REACTION YIELD
CHEMICAL REACTIONS
CHEMICAL REACTORS
DEHYDROGENATION
ELEMENTS
ETHANE
HYDROCARBONS
MATHEMATICAL MODELS
MEMBRANES
METALS
OPERATION
ORGANIC COMPOUNDS
OXIDES
OXYGEN COMPOUNDS
PERFORMANCE
PLATINUM
PLATINUM METALS
SEPARATION PROCESSES
TRANSITION ELEMENTS
YIELDS