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U.S. Department of Energy
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A new approach in ultrapurification of coal by selective flocculation

Technical Report ·
DOI:https://doi.org/10.2172/6937410· OSTI ID:6937410
The mathematical and computational model developed for predicting optimum selectivity achievable with a polymer has been successfully verified experimentally. Adsorption density of polymer SF 362 on coal and coal pyrite was measured using the depletion method. Values of {Upsilon}{sub R} (active sites ratio) and {Theta} (fractional surface coverage) were computed using the adsorption data. The mathematical model predicted a low selectivity in separating coal pyrite from coal which was also verified by selective flocculation tests. FTIR surface area and size distribution analysis indicated that mineral matter associated with both coal and coal pyrite samples can adversely affect the performance of the polymer in the selective flocculation process. Adsorption tests are in progress to identify experimental conditions (dispersant, pH, flocculent) yielding a higher value of {Upsilon}{sub R} so that the desired separation of coal pyrite from coal can be obtained. 2 refs., 8 figs., 3 tabs.
Research Organization:
Florida Univ., Gainesville, FL (USA). Mineral Resources Research Center
Sponsoring Organization:
DOE/FE
DOE Contract Number:
FG22-88PC88917
OSTI ID:
6937410
Report Number(s):
DOE/PC/88917-T4; ON: DE90011036
Country of Publication:
United States
Language:
English