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A new approach in ultrapurification of coal by selective flocculation: Quarterly report

Technical Report ·
DOI:https://doi.org/10.2172/6209554· OSTI ID:6209554
 [1]
  1. Department of Materials Science and Engineering, University of Florida, Gainesville, FL (United States)
Preparation of coal, coal refuse, quartz and clay samples along with proximate and ultimate analyses of coal and coal refuse were completed. The coal pyrite sample is expected to be received soon. Several polymers of different nature, ionic character and molecular weight were examined for their potential as selective flocculants for only coal or coal refuse. Based on single component flocculation tests, Superfloc 362 (polyacrylamide), (highly cationic), exhibited selectivity towards flocculating quartz/coal refuse. Superfloc 206 (acrylate/acrylamide copolymer), highly anionic, on the other hand, seems to flocculate coal and clays. Flocculation tests of the coal-quartz system with Superfloc 362 indicated the possibility of separating coal from the mixture. Mathematical simulation of selective flocculation of coal/clay and coal/quartz with respect to the effect of the active sites ratio at two levels of impurity content has been completed. It is indicated that selectivity in these systems is possible even when the active sites ratio is low. In other words, it is not necessary to completely eliminate the active sites (for polymer adsorption) on the inert component to achieve the desired separation. 17 refs., 11 figs., 3 tabs.
Research Organization:
Florida Univ., Gainesville, FL (USA). Dept. of Materials Science and Engineering
Sponsoring Organization:
USDOE
DOE Contract Number:
FG22-88PC88917
OSTI ID:
6209554
Report Number(s):
DOE/PC/88917-T1; ON: DE89010820
Country of Publication:
United States
Language:
English