Reactivity of methylbenzenes in reactions with peroxide radicals
Journal Article
·
· Kinet. Catal. (Engl. Transl.); (United States)
OSTI ID:6930247
We have measured the rate constants of the reaction of cumyl and tetralyl peroxide radicals with certain halogenated toluenes and xylenes in the range 393-423 K. It has been established that substituents in the para position relative to the methyl group exhibit a resonance effect. It is shown that the rate constants for primary (radical from p-xylene), secondary, and tertiary peroxide radicals reacting with p-xylene vary in the ratio 30:20:1-2.
- Research Organization:
- Institute of Physical Organic Chemistry, Minsk (USSR)
- OSTI ID:
- 6930247
- Journal Information:
- Kinet. Catal. (Engl. Transl.); (United States), Journal Name: Kinet. Catal. (Engl. Transl.); (United States) Vol. 28:5; ISSN KICAA
- Country of Publication:
- United States
- Language:
- English
Similar Records
On the reactivity of methylbenzenes
Kinetic regularities of interaction of zinc dialkyldithiocarbamates with peroxide radicals and cumyl hydroperoxide
Methylbenzene cation radical [alpha]-fragmentation selectivities revealed in SET-photoadditions of p-xylene derivatives to 1,4-dicyanonaphthalene
Journal Article
·
Sun Nov 14 23:00:00 EST 2010
· Combustion and Flame
·
OSTI ID:21379823
Kinetic regularities of interaction of zinc dialkyldithiocarbamates with peroxide radicals and cumyl hydroperoxide
Journal Article
·
Thu Dec 31 23:00:00 EST 1981
· Pet. Chem. USSR (Engl. Transl.); (United States)
·
OSTI ID:5984919
Methylbenzene cation radical [alpha]-fragmentation selectivities revealed in SET-photoadditions of p-xylene derivatives to 1,4-dicyanonaphthalene
Journal Article
·
Thu Feb 11 23:00:00 EST 1993
· Journal of Organic Chemistry; (United States)
·
OSTI ID:6304451
Related Subjects
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ACTIVATION ENERGY
ALKYLATED AROMATICS
AROMATICS
BROMINATED AROMATIC HYDROCARBONS
CATALYSIS
CATALYTIC EFFECTS
CHEMICAL REACTION KINETICS
CHEMICAL REACTIONS
CHLORINATED AROMATIC HYDROCARBONS
ENERGY
HALOGENATED AROMATIC HYDROCARBONS
HOMOGENEOUS CATALYSIS
HYDROCARBONS
KINETICS
ORGANIC BROMINE COMPOUNDS
ORGANIC CHLORINE COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
OXIDATION
OXIDIZERS
OXYGEN COMPOUNDS
PEROXIDES
PEROXY RADICALS
RADICALS
REACTION KINETICS
REDOX POTENTIAL
TOLUENE
XYLENE-PARA
XYLENES
400201* -- Chemical & Physicochemical Properties
ACTIVATION ENERGY
ALKYLATED AROMATICS
AROMATICS
BROMINATED AROMATIC HYDROCARBONS
CATALYSIS
CATALYTIC EFFECTS
CHEMICAL REACTION KINETICS
CHEMICAL REACTIONS
CHLORINATED AROMATIC HYDROCARBONS
ENERGY
HALOGENATED AROMATIC HYDROCARBONS
HOMOGENEOUS CATALYSIS
HYDROCARBONS
KINETICS
ORGANIC BROMINE COMPOUNDS
ORGANIC CHLORINE COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
OXIDATION
OXIDIZERS
OXYGEN COMPOUNDS
PEROXIDES
PEROXY RADICALS
RADICALS
REACTION KINETICS
REDOX POTENTIAL
TOLUENE
XYLENE-PARA
XYLENES