Separation of aromatic and polar compounds in fossil fuel liquids by liquid chromatography

Journal Article · Fri Jul 01 00:00:00 EDT 1983 · Anal. Chem.; (United States)

DOI:https://doi.org/10.1021/ac00259a042· OSTI ID:6923115

Matsunaga, A

A study was made on the application of normal-phase liquid chromatography for the separation of aromatic and polar compounds in fossil fuel liquids. Several commercially available packings including chemically bonded phases (NO/sub 2/, NH/sub 2/,CN, and sulfonic acid), silica, alumina, and porous polystyrene gel were compared for the separation of aromatic compounds by ring number, separation of polar compounds (nitrogen- and oxygen-containing compounds) from polynuclear aromatic hydrocarbons and the resolution between polar compounds by functional group. Model compounds expected to be present in these liquids were used for the evaluation of the packings. In the case of fuel liquid samples, the chromatographic behavior of each compound class varied according to their source and boiling range. 3 figures, 4 tables.

• Research Organization: Nippon Mining Co. Ltd., Niizo-Minami, Japan
• OSTI ID: 6923115
• Journal Information: Anal. Chem.; (United States), Journal Name: Anal. Chem.; (United States) Vol. 55:8; ISSN ANCHA
• Country of Publication: United States
• Language: English

Related Subjects

01 COAL, LIGNITE, AND PEAT
010600 -- Coal
Lignite
& Peat-- Properties & Composition
02 PETROLEUM
020400 -- Petroleum-- Processing
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400105* -- Separation Procedures
ALKANES
ALUMINIUM COMPOUNDS
ALUMINIUM OXIDES
AMINES
AROMATICS
AZAARENES
AZINES
AZOLES
CAPACITY
CHALCOGENIDES
CHEMICAL ANALYSIS
CHROMATOGRAPHY
COAL TAR
COLUMN PACKING
COMPARATIVE EVALUATIONS
CONDENSED AROMATICS
CYANIDES
DATA
ENERGY SOURCES
EXPERIMENTAL DATA
FOSSIL FUELS
FUELS
HETEROCYCLIC COMPOUNDS
HEXANE
HYDROCARBONS
HYDROXY COMPOUNDS
INFORMATION
LIQUID COLUMN CHROMATOGRAPHY
MATERIALS
METHYLENE CHLORIDE
MINERALS
NITROGEN COMPOUNDS
NITROGEN OXIDES
NITROUS OXIDE
NUMERICAL DATA
ORGANIC ACIDS
ORGANIC CHLORINE COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
ORGANIC POLYMERS
ORGANIC SOLVENTS
ORGANIC SULFUR COMPOUNDS
OTHER ORGANIC COMPOUNDS
OXIDE MINERALS
OXIDES
OXYGEN COMPOUNDS
PACKINGS
PETROCHEMICALS
PETROLEUM
PETROLEUM FRACTIONS
PETROLEUM PRODUCTS
PHENOLS
PLASTICS
POLYMERS
POLYOLEFINS
POLYSTYRENE
POLYVINYLS
PYRIDINES
PYRROLES
QUINOLINES
SEPARATION PROCESSES
SILICA
SILICON COMPOUNDS
SILICON OXIDES
SOLVENTS
SPECIFICITY
SULFONIC ACIDS
SYNTHETIC MATERIALS
TAR
TIME DEPENDENCE