Structural characterization of [((hexamethylbenzene)Ru)[sub 2]([mu]-SPh)[sub 3]]Cl[center dot]2CHCl[sub 3]
Journal Article
·
· Inorganic Chemistry; (United States)
- Univ. of Colorado, Boulder (United States)
In recent years there has been an increased interest in ruthenium complexes with sulfur donor ligands, in part because of the high catalytic activity of RuS[sub 2] in various hydrotreating processes. As a part of this development, many examples of ruthenium thiolate complexes have been reported. During the course of work to prepare mononuclear ruthenium complexes with both alkyl and sulfur donor ligands, the authors have isolated and characterized new dinuclear complexes with bridging thiolate ligands. They report here the synthesis and structural characterization of a ruthenium thiolate complex which contains hexamethylbenzene (HMB) as the supporting ligand. The structure permits a comparison with previously reported analogous structures containing pentamethylcyclopentadienyl ligands.
- OSTI ID:
- 6915817
- Journal Information:
- Inorganic Chemistry; (United States), Journal Name: Inorganic Chemistry; (United States) Vol. 31:9; ISSN 0020-1669; ISSN INOCAJ
- Country of Publication:
- United States
- Language:
- English
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OSTI ID:420988
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Related Subjects
01 COAL, LIGNITE, AND PEAT
010405 -- Coal
Lignite
& Peat-- Hydrogenation & Liquefaction
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
BOND ANGLE
BOND LENGTHS
CHEMICAL SHIFT
COHERENT SCATTERING
COMPLEXES
CRYSTAL LATTICES
CRYSTAL STRUCTURE
DIFFRACTION
DIMENSIONS
LENGTH
LIGANDS
MONOCLINIC LATTICES
NMR SPECTRA
ORGANIC COMPOUNDS
ORGANIC SULFUR COMPOUNDS
RUTHENIUM COMPLEXES
SCATTERING
SPECTRA
STRUCTURAL CHEMICAL ANALYSIS
THIOLS
TRANSITION ELEMENT COMPLEXES
X-RAY DIFFRACTION
010405 -- Coal
Lignite
& Peat-- Hydrogenation & Liquefaction
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
BOND ANGLE
BOND LENGTHS
CHEMICAL SHIFT
COHERENT SCATTERING
COMPLEXES
CRYSTAL LATTICES
CRYSTAL STRUCTURE
DIFFRACTION
DIMENSIONS
LENGTH
LIGANDS
MONOCLINIC LATTICES
NMR SPECTRA
ORGANIC COMPOUNDS
ORGANIC SULFUR COMPOUNDS
RUTHENIUM COMPLEXES
SCATTERING
SPECTRA
STRUCTURAL CHEMICAL ANALYSIS
THIOLS
TRANSITION ELEMENT COMPLEXES
X-RAY DIFFRACTION