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Porphyrins 20. * interaction of 2-formyl-5,10,15,20-tetraphenylporphyrin with CH acids

Journal Article · · Chem. Heterocycl. Compd. (Engl. Transl.); (United States)
OSTI ID:6909413
The reactions of 2-formyl-5,10,15-20-tetraphenylporphyrin (Ia) with nitromethane and of its Cu complex (Ib) with nitromethane, malonic acid, and its esters have been investigated. On interacting porphyrins (Ia,b) with nitromethane in AcOH/BuNH/sub 2/ the 2-(2-nitrovinyl)porphyrins (IIa,b) were formed, in liquid NH/sub 3/ the nitroalcohols (IIIa,b) were formed, and in DMF/BuNH/sub 2/ the dinitro derivatives (IVa,b) were formed. The interaction of porphyrin (Ib) with malonic acid and its esters led to the corresponding condensation products in high yield.
Research Organization:
M.V. Lomonosov Moscow State Univ., Moscow
OSTI ID:
6909413
Journal Information:
Chem. Heterocycl. Compd. (Engl. Transl.); (United States), Journal Name: Chem. Heterocycl. Compd. (Engl. Transl.); (United States) Vol. 21:7; ISSN CHCCA
Country of Publication:
United States
Language:
English