Synthesis and characterization of gallium(III) 2-hydroxy-5,10,15,20-tetraphenylporphyrin. A novel example of a cyclic gallium(III) porphyrin trimer
- Univ. of Wroclaw (Poland)
Synthesis of the trimer, [(2-O-TPP)Ga{sup +3}]{sub 3} (2-O-TPP is a trianion of 2-hydroxy-5,10,15,20-tetraphenylporphyrin) is described. NMR spectroscopy indicates that the trimer forms in a head-to-tail arrangement. Reversible cleavagereactions of the trimer under acidic or basic conditions was studied by NMR spectroscopy.
- OSTI ID:
- 457083
- Journal Information:
- Inorganic Chemistry, Journal Name: Inorganic Chemistry Journal Issue: 5 Vol. 34; ISSN 0020-1669; ISSN INOCAJ
- Country of Publication:
- United States
- Language:
- English
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