Synthesis, characterization, and electrochemistry of ruthenium porphyrins containing a nitrosyl axial ligand
- Univ. of Houston, TX (United States); and others
Ruthenium nitrosyl porphyrins, [(TPP)Ru(NO)(H{sub 2}O)]BF{sub 4} and (TPP)Ru(NO)(ONO) (TPP = 5,10,15,20-tetraphenylporphyrin) were synthesized and characterized electrochemically and spectroscopically. NMR and mass spectra were recorded for the compounds, X-ray crystal structures were obtained, and cyclic voltammetric studies were performed. The H{sub 2}O and ONO ligands are found to be labile to pyridine replacement under certain conditions.
- OSTI ID:
- 478852
- Journal Information:
- Inorganic Chemistry, Journal Name: Inorganic Chemistry Journal Issue: 5 Vol. 35; ISSN 0020-1669; ISSN INOCAJ
- Country of Publication:
- United States
- Language:
- English
Similar Records
Characterization of singly reduced iron(II) porphyrins
Electron-nuclear coupling in nitrosyl heme proteins and in nitrosyl ferrous and oxy cobaltous tetraphenylporphyrin complexes
Electrochemical studies of the bimetallic complex formed by ruthenium(II) polypyridine and manganese(III) porphyrin
Journal Article
·
Wed Sep 16 00:00:00 EDT 1987
· J. Am. Chem. Soc.; (United States)
·
OSTI ID:5890935
Electron-nuclear coupling in nitrosyl heme proteins and in nitrosyl ferrous and oxy cobaltous tetraphenylporphyrin complexes
Journal Article
·
Mon Nov 30 23:00:00 EST 1987
· Biochemistry; (United States)
·
OSTI ID:5436029
Electrochemical studies of the bimetallic complex formed by ruthenium(II) polypyridine and manganese(III) porphyrin
Journal Article
·
Sun Oct 01 00:00:00 EDT 1995
· Journal of Coordination Chemistry
·
OSTI ID:240972