Productivity selectivity in the infrared laser induced reaction of trans-2-butene
Journal Article
·
· J. Phys. Chem.; (United States)
The infrared multiple-photon photolysis of trans-2-butene was investigated at five CO/sub 2/ wavelengths from 942 to 1031 cm/sup -1/ and at conversions from a few percent to approximately 95%. The reaction products at 50 m Torr and fluences of approximately 125 J/cm/sup 2/ were cis-2-butene, ethylene, ethane, propylene, propyne, 1,3-butadiene, 1-butene, and 2-butyne. Relative product yields of cis-2-butene and propyne varied significantly with both wavelength and conversion. The results of an investigation of the observed product selectivity are presented.
- Research Organization:
- Univ. of Minnesota, MN
- OSTI ID:
- 6909262
- Journal Information:
- J. Phys. Chem.; (United States), Journal Name: J. Phys. Chem.; (United States) Vol. 90:22; ISSN JPCHA
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201 -- Chemical & Physicochemical Properties
400500* -- Photochemistry
ALKANES
ALKENES
ALKYNES
ARRHENIUS EQUATION
BUTADIENE
BUTENES
CARBON DIOXIDE LASERS
CHEMICAL PREPARATION
CHEMICAL REACTION YIELD
CHEMICAL REACTIONS
DATA
DECOMPOSITION
DIENES
EQUATIONS
ETHANE
ETHYLENE
EXPERIMENTAL DATA
GAS LASERS
HYDROCARBONS
INFORMATION
LASERS
MULTI-PHOTON PROCESSES
NUMERICAL DATA
ORGANIC COMPOUNDS
PHOTOCHEMICAL REACTIONS
PHOTOLYSIS
POLYENES
PROPYLENE
PROPYNE
SYNTHESIS
YIELDS
400201 -- Chemical & Physicochemical Properties
400500* -- Photochemistry
ALKANES
ALKENES
ALKYNES
ARRHENIUS EQUATION
BUTADIENE
BUTENES
CARBON DIOXIDE LASERS
CHEMICAL PREPARATION
CHEMICAL REACTION YIELD
CHEMICAL REACTIONS
DATA
DECOMPOSITION
DIENES
EQUATIONS
ETHANE
ETHYLENE
EXPERIMENTAL DATA
GAS LASERS
HYDROCARBONS
INFORMATION
LASERS
MULTI-PHOTON PROCESSES
NUMERICAL DATA
ORGANIC COMPOUNDS
PHOTOCHEMICAL REACTIONS
PHOTOLYSIS
POLYENES
PROPYLENE
PROPYNE
SYNTHESIS
YIELDS