Molecular beam study of isomerization and dehydrogenation of butene on a mica surface

Journal Article · Fri Mar 30 04:00:00 EST 1979 · J. Catal.; (United States)

DOI:https://doi.org/10.1016/0021-9517(79)90047-2· OSTI ID:7101542

Loeffler, D; Haller, G L; Fenn, J B

Experimental results obtained at 650/sup 0/-850/sup 0/K in a Recycling Molecular Beam Reactor on the conversion of 1-butene to cis- and trans-2-butene, and to 1,3-butadiene on a heat-treated natural mica, a model for an amorphous silica-alumina catalyst, showed the reaction probability could be fitted for each of the three reactions by the equation P equals A exp (-E/RT), where A and E were 0.0029 and 41.9 kj/mole for cis-2-butene, 0.012 and 48.1 kj/mole for trans-2-butene, and 0.2 and 48.2 kj/mole for butadiene.

• Research Organization: Yale Univ.
• OSTI ID: 7101542
• Journal Information: J. Catal.; (United States), Journal Name: J. Catal.; (United States) Vol. 57:1; ISSN JCTLA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400301* -- Organic Chemistry-- Chemical & Physicochemical Properties-- (-1987)
ALKENES
ALUMINIUM COMPOUNDS
ALUMINIUM OXIDES
BEAMS
BUTADIENE
BUTENES
CATALYSTS
CATALYTIC EFFECTS
CHALCOGENIDES
CHEMICAL REACTION YIELD
CHEMICAL REACTIONS
DATA
DEHYDROGENATION
DIENES
EXPERIMENTAL DATA
HIGH TEMPERATURE
HYDROCARBONS
INFORMATION
ISOMERIZATION
KINETICS
MATHEMATICAL MODELS
MICA
MINERALS
MOLECULAR BEAMS
NUMERICAL DATA
ORGANIC COMPOUNDS
OXIDE MINERALS
OXIDES
OXYGEN COMPOUNDS
POLYENES
REACTION KINETICS
SILICA
SILICON COMPOUNDS
SILICON OXIDES
YIELDS