Gas phase dehydrocyclization of 1,4-butanediol. Bifunctional catalysis over reduced iron promoted by a fused catalyst

Journal Article · Wed Apr 01 00:00:00 EST 1987 · Dokl. Phys. Chem. (Engl. Transl.); (United States)

OSTI ID:6908923

Glebov, L S; Kliger, G A; Yatsenko, A E; Mikaya, A I; Zaikin, V G; Loktev, S M

The authors test a reduced-iron promoted fused catalyst comprised of divanadium pentoxide, dialuminium trioxide, and silicon dioxide in the heterogeneous dehydrocyclization of 1,4-butanediol. The reaction products were analyzed by chromatography and mass spectroscopy and include n-butanol, di-n-butylene glycol, tetrahydrofuran, butyrolactone, and 4-hydroxybutanal, as well as traces of unreacted butanediol. Kinetics and yields are analyzed from the standpoint of the catalysis mechanism.

• Research Organization: A. V. Topchiev Institute of Petrochemical Synthesis, Moscow (USSR)
• OSTI ID: 6908923
• Journal Information: Dokl. Phys. Chem. (Engl. Transl.); (United States), Vol. 290:4-6; Other Information: Translated from Dokl. Akad. Nauk SSSR; 290: No. 4-6, 1140-1141(Oct 1986)
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
ALUMINIUM OXIDES
CATALYTIC EFFECTS
BUTANEDIOLS
DEHYDROCYCLIZATION
HETEROGENEOUS CATALYSIS
IRON
SILICON OXIDES
VANADIUM OXIDES
BUTANOLS
CATALYSTS
CHEMICAL REACTION KINETICS
CHROMATOGRAPHY
GLYCOLS
LACTONES
MASS SPECTRA
MATERIALS TESTING
PH VALUE
PROMOTERS
TETRAHYDROFURAN
ALCOHOLS
ALUMINIUM COMPOUNDS
CATALYSIS
CHALCOGENIDES
CHEMICAL REACTIONS
ELEMENTS
ESTERS
FURANS
HETEROCYCLIC COMPOUNDS
HYDROXY COMPOUNDS
KINETICS
METALS
ORGANIC COMPOUNDS
ORGANIC OXYGEN COMPOUNDS
OXIDES
OXYGEN COMPOUNDS
REACTION KINETICS
SEPARATION PROCESSES
SILICON COMPOUNDS
SPECTRA
TESTING
TRANSITION ELEMENT COMPOUNDS
TRANSITION ELEMENTS
VANADIUM COMPOUNDS
400201* - Chemical & Physicochemical Properties