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X-ray structural analysis of the photolysis products of glycinate and. beta. -alaninate cobalt(III) complexes

Journal Article · · Dokl. Phys. Chem. (Engl. Transl.); (United States)
OSTI ID:6908641
The authors were recently able to isolate in crystalline form the intermediate products in the photolysis of various mixed glycinate Co(III) complexes, and have also lately isolated the intermediate products of the photolysis of analogous complexes containing longer chain anions, such as of amino-3-propionate and amino-4-butyrate. In order to determine the structures of these products it is necessary to analyze them by x-ray crystallography. In this paper they describe the structures of two compounds which contain cationic complexes isolated from UV irradiation (lambda = 254 nm) of aqueous solutions of (Coen/sub 2/(..beta..-ala))/sup 2 +/ and Codipy/sub 2/(gly))/sup 2 +/, respectively (en = ethylenediamine, dipy = 2,2'-dipyridine, gly = glycinate, and ..beta..-ala = alaninate). In both cases, the coordinates of all of the atoms, including hydrogen atoms, were determined.
Research Organization:
M. V. Lomonosov Moscow State Univ. (USSR)
OSTI ID:
6908641
Journal Information:
Dokl. Phys. Chem. (Engl. Transl.); (United States), Journal Name: Dokl. Phys. Chem. (Engl. Transl.); (United States) Vol. 290:4-6; ISSN DKPCA
Country of Publication:
United States
Language:
English