Ultraviolet laser photochemistry of halogenated methanes
Conference
·
OSTI ID:6904023
The uv laser photochemistry of CF/sub 2/Br/sub 2/, CCl/sub 4/, CCl/sub 3/F, and CCl/sub 2/F/sub 2/ was studied. The emission spectra and dynamics of the halogenated alkyl radicals formed from the excimer laser photolysis of these compounds are reported. Possible mechanistic routes are also examined. Some results are given from studies on the kinetics of CCl, CCl/sub 2/, and CClF ground state radicals with various reactants.
- Research Organization:
- Los Alamos Scientific Lab., NM (USA)
- DOE Contract Number:
- W-7405-ENG-36
- OSTI ID:
- 6904023
- Report Number(s):
- LA-UR-80-2798; CONF-801139-1
- Country of Publication:
- United States
- Language:
- English
Similar Records
UV laser photochemistry of CCl/sub 4/ and CCl/sub 3/F
Thermal conductivity of liquid halogenated ethanes under high pressures
Laser induced fluorescence studies of the reactions of barium (/sup 1/S, /sup 3/D) and strontium (/sup 1/S, /sup 3/P) with halogenated methanes
Journal Article
·
Fri Feb 29 23:00:00 EST 1980
· J. Chem. Phys.; (United States)
·
OSTI ID:5689520
Thermal conductivity of liquid halogenated ethanes under high pressures
Journal Article
·
Fri Jul 01 00:00:00 EDT 1988
· Int. J. Thermophys.; (United States)
·
OSTI ID:6420868
Laser induced fluorescence studies of the reactions of barium (/sup 1/S, /sup 3/D) and strontium (/sup 1/S, /sup 3/P) with halogenated methanes
Journal Article
·
Sat Apr 14 23:00:00 EST 1979
· J. Chem. Phys.; (United States)
·
OSTI ID:6141343
Related Subjects
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400500* -- Photochemistry
ALKYL RADICALS
CARBON TETRACHLORIDE
CHEMICAL REACTION KINETICS
CHEMICAL REACTIONS
CHLORINATED ALIPHATIC HYDROCARBONS
DECOMPOSITION
EMISSION SPECTRA
FLUORINATED ALIPHATIC HYDROCARBONS
FLUOROFORM
HALOGENATED ALIPHATIC HYDROCARBONS
KINETICS
LASERS
ORGANIC CHLORINE COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC FLUORINE COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
PHOTOCHEMICAL REACTIONS
PHOTOLYSIS
RADICALS
REACTION KINETICS
SPECTRA
400500* -- Photochemistry
ALKYL RADICALS
CARBON TETRACHLORIDE
CHEMICAL REACTION KINETICS
CHEMICAL REACTIONS
CHLORINATED ALIPHATIC HYDROCARBONS
DECOMPOSITION
EMISSION SPECTRA
FLUORINATED ALIPHATIC HYDROCARBONS
FLUOROFORM
HALOGENATED ALIPHATIC HYDROCARBONS
KINETICS
LASERS
ORGANIC CHLORINE COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC FLUORINE COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
PHOTOCHEMICAL REACTIONS
PHOTOLYSIS
RADICALS
REACTION KINETICS
SPECTRA